Abstract. Lack of real-time information on nutrient availability in
cultivated soils inherently leads to excess application of fertilizers in
agriculture. As a result, nitrate, which is a soluble, stable, and mobile
component of fertilizers, leaches below the root zone through the
unsaturated zone and eventually pollutes the groundwater and other related
water resources. Rising nitrate concentration in aquifers is recognized as a
worldwide environmental problem that contributes to water scarcity. The
development of technologies for continuous in situ measurement of nitrate
concentration in soils is essential for optimizing fertilizer application
and preventing water resource pollution by nitrate. Here we present a
conceptual approach for a monitoring system that enables in situ and
continuous measurement of nitrate concentration in soil. The monitoring
system is based on absorbance spectroscopy techniques for direct
determination of nitrate concentration in soil porewater without
pretreatment, such as filtration, dilution, or reagent supplementation. A
new analytical procedure was developed to improve measurement accuracy while
eliminating the typical measurement interference caused by soil dissolved
organic carbon. The analytical procedure was tested at four field sites over
2 years and proved to be an effective tool for nitrate analysis when
directly applied on untreated soil solution samples. A soil
nitrate-monitoring apparatus, combining specially designed optical flow
cells with soil porewater-sampling units, enabled, for the first time,
real-time continuous measurement of nitrate concentration in soils.
Real-time, high-resolution measurement of nitrate concentration in the soil
has revealed the complex variations in soil nitrate concentrations in
response to fertigation pattern. Such data are crucial for optimizing
fertilizer application and reducing pollution potential of groundwater.