Duringthe natural or man-made disasters, telecommunication plays a major role to provide communication among population, government authorities, and to carry rescue operations in the affected areas. However, due to the lack of power and damaged infrastructure it may take several days to resume the entire communication network. In this scenario, it is highly needed to have an effective and timely response to establish persistent and reliable communication. Device-to -Device (D2D) Communication is among the recent advancements to achieve greater device performance by benefiting from short distances, direct communications and the variety of users. The main objective of this work is to provide substitute access to mobile networks if they are affected partially or completely by natural disasters. So, the concept of radio frequency based energy harvesting is employed. Energy harvest will power communication devices and environmental networks. A priority-based energy efficient scheduling (EES) technique is proposed to select the clusters that have less effective signal strength. Further, an optimal communication route is discussed that reduces the loss of connectivity and assists the connection from the serviceable area to inoperable zone. The suggested scheme dramatically saves energy for both cluster heads and user equipment (UE) in crucial circumstances like disasters.