In a new high-precision experiment at the Paul Scherrer Institut (PSI), the hadronic shift (ε 1s ) and width ( 1s ) of the ground state of pionic hydrogen, which are directly connected to the pion-nucleon isospin scattering lengths, were remeasured (PSI-Experiment R-98-01 Gotta et al. 1998). The results can be confronted with recent work of effective field theories defined in the low-energy limit of quantum chromodynamics (QCD), such as, e. g., chiral perturbation theory (ChPT). In addition, 1s is connected to the pion-nucleon coupling constant f πN . A precisely known value for f πN allows an accurate determination of the Goldberger-Treiman discrepancy, which constitutes a measure of chiral symmetry breaking. This contribution is mainly devoted to describe a method for an accurate extraction of the hadronic width from the π − H data.