A reaction of tin tetra(N,N-diethylcarbamate) with phenylacetylene as a new route to tetra(phenylethynyl)tin

Levashov, A. S.; Andreev, A. A.; Buryi, D. S.; Коншин, В. В.

doi:10.1007/s11172-014-0508-8

Cited by 12 publications

(6 citation statements)

References 10 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…A further example is given by the β-diketonato complex [Tb(dbm) 3 ], which was obtained upon reaction of [Tb(O 2 CNBu 2 ) 3 ] with dibenzoylmethane (Hdbm) [153]. A new entry into this category is represented by terminal alkynes: [Sn(O 2 CNEt 2 )] 4 reacts with phenylacetylene in refluxing toluene, to afford the homoleptic Sn(IV) alkynyl derivative [Sn(CCPh) 4 ] [296].…”

Section: Scheme 30 Possible Reactions Of An Electrophile E With a Camentioning

confidence: 99%

Recent Advances in the Chemistry of Metal Carbamates

et al. 2020

View full text Add to dashboard Cite

Following a related review dating back to 2003, the present review discusses in detail the various synthetic, structural and reactivity aspects of metal species containing one or more carbamato ligands, representing a large family of compounds across all the periodic table. A preliminary overview is provided on the reactivity of carbon dioxide with amines, and emphasis is given to recent findings concerning applications in various fields.

show abstract

Section: Scheme 30 Possible Reactions Of An Electrophile E With a Camentioning

confidence: 99%

Recent Advances in the Chemistry of Metal Carbamates

et al. 2020

View full text Add to dashboard Cite

show abstract

“…carried out on 3 showing a continuous weight loss between room temperature and 300 °C (and resulting in the recovery of SnO2 as final residue). Beyond their interest as precursors for the deposition of tin oxide films [4,5], tin tetracarbamates were also used as versatile reactants for various organometallic and organic syntheses leading to alkoxystannanes [47], tetraalkynylstannanes [48] (Scheme 12), and O-silylurethanes [49]. [51].…”

Section: X-ray Crystal Structuresmentioning

confidence: 99%

CO2 Derivatives of Molecular Tin Compounds. Part 2: Carbamato, Formato, Phosphinoformato and Metallocarboxylato Complexes

Plasseraud

2021

Inorganics

View full text Add to dashboard Cite

Single-crystal X-ray diffraction structures of organotin compounds bearing hemicarbonate and carbonate ligands were recently reviewed by us—“CO2 Derivatives of Molecular Tin Compounds. Part 1: Hemicarbonato and Carbonato Complexes”, Inorganics2020, 8, 31—based on crystallographic data available from the Cambridge Structural Database. Interestingly, this first collection revealed that most of the compounds listed were isolated in the context of studies devoted to the reactivity of tin precursors towards carbon dioxide, at atmospheric pressure or under pressure, thus highlighting the suitable disposition of Sn to fix CO2. In the frame of a second part, the present review carries on to explore CO2 derivatives of molecular tin compounds by describing successively the complexes with carbamato, formato, and phosphinoformato ligands, and obtained from insertion reactions of carbon dioxide into Sn–X bonds (X = N, H, P, respectively). The last chapter is devoted to X-ray structures of transition metal/tin CO2 complexes exhibiting metallocarboxylato ligands. As in Part 1, for each tin compound reported and when described in the original study, the structural descriptions are supplemented by synthetic conditions and spectroscopic data.

show abstract

“…Recently, we reported the Stille-type coupling reaction of tetraalkynylstannanes with aryl halides leading to aryl acetylenes and SnHal4 [12] and aldehydes leading to alkynyl ketones [13,14]. Earlier, we developed convenient methods for preparation of tetraalkinyltin species from either SnCl4 [15] or tin tetra(N,N-diethylcarbamate) [16].…”

Section: Introductionmentioning

confidence: 99%