A quinary layer transition metal oxide of NaNi1/4Co1/4Fe1/4Mn1/8Ti1/8O2 as a high-rate-capability and long-cycle-life cathode material for rechargeable sodium ion batteries

Yue, Ji-Li; Yin, Wenwen; Cao, Minghui; Shadike, Zulipiya; Zhou, Yong‐Ning; Fu, Zheng‐Wen

doi:10.1039/c5cc06585b

Cited by 79 publications

(41 citation statements)

References 34 publications

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“…The electrochemical Na-ion intercalation behavior of layered transition-metal oxides was examined by Delmas and co-workers in the early 1980s. The significant role of the inactive Ti ions in promoting the battery performance of layered sodium-containing electrodes is also found in other reports [39][40][41][42] and has been reviewed in a previous paper. However, these authors have identified many structural properties of layered and trigonal-prismatic interstitial sites, respectively.…”

Section: Layered Transition-metal Oxidessupporting

confidence: 64%

“…The cycle life after 100 electrochemical cycles can be 93.2%, and more than 60% of the initial discharge capacity can be achieved even at a rate of 5 C. During the charging/discharge process, the Ni redox changes between divalent and tetravalent, while the Ti ions remain tetravalent. The significant role of the inactive Ti ions in promoting the battery performance of layered sodium‐containing electrodes is also found in other reports and has been reviewed in a previous paper …”

Section: Cathode Materialsmentioning

confidence: 98%

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Exploration of Advanced Electrode Materials for Rechargeable Sodium‐Ion Batteries

Sun

Guo

Zhou

2018

Advanced Energy Materials

219

131

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As the rapid growth of the lithium‐ion battery (LIB) market raises concerns about limited lithium resources, rechargeable sodium‐ion batteries (SIBs) are attracting growing attention in the field of electrical energy storage due to the large abundance of sodium. Compared with the well‐developed commercial LIBs, all components of the SIB system, such as the electrode, electrolyte, binder, and separator, need further exploration before reaching a practical industrial application level. Drawing lessons from the LIB research, the SIB electrode materials are being extensively investigated, resulting in tremendous progress in recent years. In this article, the progress of the research on the development of electrode materials for SIBs is summarized. A variety of new electrode materials for SIBs, including transition‐metal oxides with a layered or tunnel structure, polyanionic compounds, and organic molecules, have been proposed and systematically investigated. Several promising materials with moderate energy density and ultra‐long cycling performance are demonstrated. Appropriate doping and/or surface treatment methodologies are developed to effectively promote the electrochemical properties. The challenges of and opportunities for exploiting satisfactory SIB electrode materials for practical applications are outlined.

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Section: Layered Transition-metal Oxidessupporting

confidence: 64%

Section: Cathode Materialsmentioning

confidence: 98%

Exploration of Advanced Electrode Materials for Rechargeable Sodium‐Ion Batteries

Sun

Guo

Zhou

2018

Advanced Energy Materials

219

131

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“…They found that P2 + O3 integration can be easily generated when a certain amount of Li + is doped into the TMO 2 layers. Yue et al introduced the quinary layered NaNi 1/4 Co 1/4 Fe 1/4 Mn 1/8 Ti 1/8 O 2 as high rate capability material . The charge/discharge curves are much smoother than those of single or binary iron‐containing oxides.…”

Section: Iron‐ and Mn‐based Layered Oxide Cathodesmentioning

confidence: 99%

High‐Abundance and Low‐Cost Metal‐Based Cathode Materials for Sodium‐Ion Batteries: Problems, Progress, and Key Technologies

Chen

Liu

Wang

et al. 2019

Advanced Energy Materials

208

149

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Recently, room-temperature stationary sodium-ion batteries (SIBs) have received extensive investigations for large-scale energy storage systems (EESs) and smart grids due to the huge natural abundance and low cost of sodium. The SIBs share a similar "rocking-chair" sodium storage mechanism with lithium-ion batteries; thus, selecting appropriate electrodes with a low cost, satisfactory electrochemical performance, and high reliability is the key point for the development for SIBs. On the other hand, the carefully chosen elements in the electrodes also largely determine the cost of SIBs. Therefore, earth-abundantmetal-based compounds are ideal candidates for reducing the cost of electrodes. Among all the high-abundance and low-cost metal elements, cathodes containing iron and/or manganese are the most representative ones that have attracted numerous studies up till now. Herein, recent advances on both ironand manganese-based cathodes of various types, such as polyanionic, layered oxide, MXene, and spinel, are highlighted. The structure-function property for the iron-and manganese-based compounds is summarized and analyzed in detail. With the participation of iron and manganese in sodium-based cathode materials, real applications of room-temperature SIBs in large-scale EESs will be greatly promoted and accelerated in the near future.

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“…O3‐NaFe 0.3 Ni 0.7 O 2 delivers an initial discharge capacity of 135 mAh g −1 with most of the capacity located in a high‐voltage region of 2.5–3.8 V . O3 layered materials with various transition metal compositions have also been studied; for example, Fu and co‐workers have reported on the Fe–Co–Ni–Ti and Fe–Co–Ni–Ti–Mn systems, which demonstrate a long‐term cyclability and a high rate capability . Hu and co‐workers have reported an air‐stable and Co/Ni‐free layered metal oxide of O3‐Na 0.9 [Cu 0.22 Fe 0.30 Mn 0.48 ]O 2 , which exhibits a reversible capacity of 100 mAh g −1 at an average storage voltage of 3.2 V with a long cycle life .…”

Section: Cathode Materialsmentioning

confidence: 99%

Recent Progress in Iron‐Based Electrode Materials for Grid‐Scale Sodium‐Ion Batteries

Fang

Chen

Xiao

et al. 2018

Small

156

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Grid-scale energy storage batteries with electrode materials made from low-cost, earth-abundant elements are needed to meet the requirements of sustainable energy systems. Sodium-ion batteries (SIBs) with iron-based electrodes offer an attractive combination of low cost, plentiful structural diversity and high stability, making them ideal candidates for grid-scale energy storage systems. Although various iron-based cathode and anode materials have been synthesized and evaluated for sodium storage, further improvements are still required in terms of energy/power density and long cyclic stability for commercialization. In this Review, progress in iron-based electrode materials for SIBs, including oxides, polyanions, ferrocyanides, and sulfides, is briefly summarized. In addition, the reaction mechanisms, electrochemical performance enhancements, structure-composition-performance relationships, merits and drawbacks of iron-based electrode materials for SIBs are discussed. Such iron-based electrode materials will be competitive and attractive electrodes for next-generation energy storage devices.

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A quinary layer transition metal oxide of NaNi_1/4Co_1/4Fe_1/4Mn_1/8Ti_1/8O₂ as a high-rate-capability and long-cycle-life cathode material for rechargeable sodium ion batteries

Abstract: A well-crystallized single-phase quinary layer transition metal oxide of NaNi1/4Co1/4Fe1/4Mn1/8Ti1/8O2 was successfully synthesized. It exhibited excellent cycle performance and high rate capability as a cathode material for sodium-ion batteries.

Cited by 79 publications

References 34 publications

Exploration of Advanced Electrode Materials for Rechargeable Sodium‐Ion Batteries

Exploration of Advanced Electrode Materials for Rechargeable Sodium‐Ion Batteries

High‐Abundance and Low‐Cost Metal‐Based Cathode Materials for Sodium‐Ion Batteries: Problems, Progress, and Key Technologies

Recent Progress in Iron‐Based Electrode Materials for Grid‐Scale Sodium‐Ion Batteries

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