Abstract. In this paper we study a model for phase separation and damage in thermoviscoelastic materials. The main novelty of the paper consists in the fact that, in contrast with previous works in the literature (cf., e.g., [21,22]), we encompass in the model thermal processes, nonlinearly coupled with the damage, concentration and displacement evolutions. More in particular, we prove the existence of "entropic weak solutions", resorting to a solvability concept first introduced in [10] in the framework of Fourier-Navier-Stokes systems and then recently employed in [9,38] for the study of PDE systems for phase transition and damage. Our global-in-time existence result is obtained by passing to the limit in a carefully devised time-discretization scheme.