The discovery of quasicrystals with crystallographically forbidden rotational symmetries has changed the notion of the ordering in materials, yet little is known about the dynamical emergence of such exotic forms of order. Here we theoretically study a nonequilibrium cavity-QED setup realizing a zero-temperature quantum phase transition from a homogeneous Bose-Einstein condensate to a quasicrystalline phase via collective superradiant light scattering. Across the superradiant phase transition, collective light scattering creates a dynamical, quasicrystalline optical potential for the atoms. Remarkably, the quasicrystalline potential is "emergent" as its eight-fold rotational symmetry is not present in the Hamiltonian of the system, rather appears solely in the low-energy states. For sufficiently strong two-body contact interactions between atoms, a quasicrystalline order is stabilized in the system, while for weakly interacting atoms the condensate is localized in one or few of the deepest minima of the quasicrystalline potential.Introduction.-Quasicrystals are quasiordered (or orientationally ordered) materials with no exact translational symmetry, rather with crystallographically forbidden rotational symmetries [1]. They possess rotational symmetries, such as five-, seven-, eight-fold rotational symmetries, as discovered from their diffraction patterns first by Shechtman et al. in 1984 [2]. Therefore, they are not periodic and do not belong to any of the crystallographic space groups. Interestingly, quasicrystals, related to aperiodic tilings, can be considered as projections of higher dimensional periodic lattices [3][4][5]. Despite extensive theoretical and experimental research since their discovery [6], there are still many fundamental open questions concerning the formation and nature of quasicrystals. For instance, it is still not completely clear whether quasicrystals are only entropy-stabilized high-temperature states or can also be thermodynamically stable at low temperatures [7]. In particular, the conditions and nature of quasicrystal growth are under debate with a lack of a generally accepted model.