2011
DOI: 10.1016/j.jallcom.2011.07.064
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A precursor route to synthesize mesoporous γ-MnO2 microcrystals and their applications in lithium battery and water treatment

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Cited by 35 publications
(22 citation statements)
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“…[17] As is wellknown that MnO 2 can form several kinds of polymorphs such as ␣-, ␤-, ␥-and ␦-types according to the different linkage patterns of basic unit [MnO 6 ] octahedral. Among all the structures, ␥-MnO 2 which is considered to be an intergrowth of ramsdellite (1 × 2 tunnels) and pyrolusite (1 × 1 tunnels) have wide applications in electrochemical supercapacitors [27], lithium ion battery [28,29] and dry-cell batteries [30]. In previous studies, PANI in its emeraldine salt form shows characteristic peak at 20.8 • .…”
Section: Xrdmentioning
confidence: 99%
“…[17] As is wellknown that MnO 2 can form several kinds of polymorphs such as ␣-, ␤-, ␥-and ␦-types according to the different linkage patterns of basic unit [MnO 6 ] octahedral. Among all the structures, ␥-MnO 2 which is considered to be an intergrowth of ramsdellite (1 × 2 tunnels) and pyrolusite (1 × 1 tunnels) have wide applications in electrochemical supercapacitors [27], lithium ion battery [28,29] and dry-cell batteries [30]. In previous studies, PANI in its emeraldine salt form shows characteristic peak at 20.8 • .…”
Section: Xrdmentioning
confidence: 99%
“…3 In this respect, manifold anode materials, such as Si, transition-metal oxides, and their analogues, have been explored as an essential constituent in LIBs. [8][9][10][11] In general, the shape guidingmechanism results in MnCO 3 being an unavoidable hot topic. In particular, MnCO 3 materials are widely used as sacrificial templates to synthesize the respective derivative metal oxides via thermal conversion with the target morphologies.…”
Section: Introductionmentioning
confidence: 99%
“…Among the nanomaterials, the manganese oxides with various types of crystalline structures, such as -, -, -MnO 2 , have been extensively studied owing to their structural varieties and excellent chemical characteristics. As a result, they have been applied to different areas such as batteries, molecular sieves, catalysts, and adsorbents [16,17]. However, the use ofMnO 2 nanomaterial as a solid phase for the preconcentration of cobalt from seawater has still been rarely studied.…”
Section: Journal Of Chemistrymentioning
confidence: 99%