A Powerful P−N Connection: Preparative Approaches, Reactivity, and Applications of P‐Stereogenic Aminophosphines
Tanja Huber,
Jonathan O. Bauer
Abstract:For more than five decades, P‐stereogenic aminophosphine chalcogenides and boranes have attracted scientific attention and are still in the focus of ongoing research. In the last years, novel transition metal‐based synthesis methods have been discovered, in addition to the long‐known use of chiral auxiliaries. Enantiomerically pure compounds with N–P+–X‐ (X = O, S, BH3) motifs served as valuable reactive building blocks to provide new classes of organophosphorus derivatives, thereby preserving the stereochemic… Show more
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