A polymer rigidity probe based on ultralong organic room temperature phosphorescence of a new skeleton benzo[4,5]imidazo[1,2-<i>a</i>]pyridine

Ma, Jiaxin; Bai, Jingjuan; Han, Lin; Zhang, Xingda; Liu, Yiran; Bu, Lijuan; Li, Zewei; Chen, Mingxing; Ma, Zhimin; Ma, Zhiyong

doi:10.1039/d4tc02846e

J. Mater. Chem. C

2024

DOI: 10.1039/d4tc02846e

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A polymer rigidity probe based on ultralong organic room temperature phosphorescence of a new skeleton benzo[4,5]imidazo[1,2-a]pyridine

Jiaxin Ma,

Jingjuan Bai,

Lin Han

et al.

Abstract: We report a new backbone, BNPy. Copolymerizing MA and AA with BNPy derivatives extended UORTP to over 10 s. For BNPy-1, the τp is closely related to the trend of matrix Tg. Thus, BNPy-1 can be used as an efficient polymer rigidity (or Tg) probe.

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A polymer rigidity probe based on ultralong organic room temperature phosphorescence of a new skeleton benzo[4,5]imidazo[1,2-a]pyridine

Abstract: We report a new backbone, BNPy. Copolymerizing MA and AA with BNPy derivatives extended UORTP to over 10 s. For BNPy-1, the τp is closely related to the trend of matrix Tg. Thus, BNPy-1 can be used as an efficient polymer rigidity (or Tg) probe.

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References 46 publications

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