A Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3-Dicarboxylate

Çolak, Alper Tolga; Pamuk, Gönül; Uzun, Nazlı; Yeşılel, Okan Zafer; Semerci, Fatih; Günay, Handan; Büyükgüngör, Orhan

doi:10.1007/s10904-012-9798-1

Cited by 8 publications

(2 citation statements)

References 29 publications

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“…5-Methyl-1,3,4thiadiazol-2-amine (tda) can act as a bridging or chelating ligand with its three N atoms. Although Ag I -H 2 pdc coordination compounds have been investigated (Wang et al, 2014;Colak et al, 2013), the Ag I -tda-H 2 pdc system has not yet been documented. We describe herein the infinite one-dimensional Ag I coordination polymer {[Ag 2 (pdc)(tda) 3 ]ÁH 2 OÁC 2 H 5 OH} n , (I).…”

Section: Introductionmentioning

confidence: 99%

A one-dimensional silver(I) coordination polymer based on 5-methyl-1,3,4-thiadiazol-2-amine and pyridine-2,3-dicarboxylate

Liu

et al. 2017

Acta Crystallogr C

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The bifunctional pyridine-2,3-dicarboxylic acid (Hpdc) ligand has one N atom and four O atoms, which could bind more than one Ag centre with diverse binding modes. A novel infinite one-dimensional Ag coordination polymer, namely catena-poly[[silver(I)-(μ-pyridine-2,3-dicarboxylato-κN:O)-silver(I)-tris(μ-5-methyl-1,3,4-thiodiazol-2-amine-κN:N')] monohydrate ethanol monosolvate], {[Ag(CHNO)(CHNS)]·HO·CHOH}, has been synthesized using Hpdc and 5-methyl-1,3,4-thiadiazol-2-amine (tda), and characterized by single-crystal X-ray diffraction. One Ag atom is located in a four-coordinated AgN tetrahedral geometry and the other Ag atom is in a tetrahedral AgNO geometry. A dinuclear Ag cluster formed by three tda ligands with a paddelwheel configuration is bridged by the dianionic pdc ligand into a one-dimensional coordination polymer. Interchain N-H...O hydrogen bonds extend the one-dimensional chains into an undulating two-dimensional sheet. The sheets are further packed into a three-dimensional supramolecular framework by interchain N-H...O hydrogen bonds.

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Section: Introductionmentioning

confidence: 99%

A one-dimensional silver(I) coordination polymer based on 5-methyl-1,3,4-thiadiazol-2-amine and pyridine-2,3-dicarboxylate

Liu

et al. 2017

Acta Crystallogr C

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“…Many novel supramolecular complexes can be constructed by two kinds of metal complexes: One is metal-organic frameworks [4][5][6][7][8]; another is monomeric complex [9]. Based on the two kinds of complexes, supermolecule can be produced by non-covalent interactions [10,11], such as hydrogen bonding, π-π interactions, metal-metal interactions, and so on.…”

Section: Introductionmentioning

confidence: 99%

Syntheses, structures, and characterizations of two new lead (II) supramolecular complexes containing 4-aminobenzenesulfonate ligand

Cheng

Tang

Zhang

2014

Main Group Chemistry

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Two new lead (II) complexes, {[Pb(4-abs)(4,4 -bipy) 2 (H 2 O) 3 ]·(4-abs)} n (1) and [Pb(4-abs) 2 (phen) 2 (H 2 O)] (2), have been synthesized and characterized by elemental analyses, FTIR, thermal analyses, fluorescent spectra, and single-crystal X-ray analyses, where 4-abs is 4-aminobenzenesulfonate anion, 4,4 -bipy is 4,4 -bipyridine, phen is 1,10-phenanthroline. In these two complexes 4-abs shows three different modes, in complex 1 4-abs plays two roles: One serves as a bridging ligand, another is deprotonated and does not coordinate to the Pb atom, in complex 2 the 4-abs is a monodentate ligand. The structure of complex 1 is a one-dimensional polymer, whereas complex 2 is monomeric species. Intermolecular π-π interactions and hydrogen bonds are observed in these two complexes, which stabilize the crystal packing and give rise to supramolecular architectures.

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A New Photoluminescent and Antibacterial Polymeric Silver(I) Complex Generated from Pyridine-2,3-dicarboxylic Acid

Alisir

Sarıboğa

Topçu

et al. 2013

J Inorg Organomet Polym

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A Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3-Dicarboxylate

Cited by 8 publications

References 29 publications

A one-dimensional silver(I) coordination polymer based on 5-methyl-1,3,4-thiadiazol-2-amine and pyridine-2,3-dicarboxylate

A one-dimensional silver(I) coordination polymer based on 5-methyl-1,3,4-thiadiazol-2-amine and pyridine-2,3-dicarboxylate

Syntheses, structures, and characterizations of two new lead (II) supramolecular complexes containing 4-aminobenzenesulfonate ligand

A New Photoluminescent and Antibacterial Polymeric Silver(I) Complex Generated from Pyridine-2,3-dicarboxylic Acid

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