Highway toll booth workers have been reported to be at an increased risk of occupational lung cancer. Moreover, insufficient studies have been performed on exposure assessment of workers at highway toll booths. Elemental carbon (EC), black carbon (BC), and respirable crystalline silica (RCS) concentrations were measured at highway toll booths in Gyeongsangbuk-do (Republic of Korea). The particle number (PN) concentration and size distribution of ultrafine particle were measured using three SMPS devices. The average concentration of the EC inside the booth was 3.3 μg/m 3 , with the maximum being 5.8 μg/m 3. The concentrations of EC were highest for booths that operated exclusively for trucks. The average PN concentration inside the booth was 3.54 × 10 4 cm-3 , approximately 5-fold higher than the reference indoor background. The average BC concentration in the booths were approximately 8 μg/m 3 , and the instantaneous peak concentration was 271 μg/m 3. The RCS was below the detection limit in all samples. This study revealed that toll workers were most frequently exposed to diesel engine particle less than 100 nm, with an extremely high respiratory deposition rate. Therefore, a respiratory protection program is necessary to safeguard these workers against vehicle-related pollutants.