Compared with polypropylene homopolymer
(PPH), β-nucleating
agent (β-NA) usually induces less β-phase in polypropylene
random copolymer (PPR) with comonomer inserted. A widely held view
is that unfavorable β-growth kinetically caused by the insertion
of comonomer contributes to a decreased relative content of β-phase
(k
β) in PPR. To further understand
the decreased k
β in PPR, we separately
investigated the nucleation and growth behavior of various isotactic
polypropylenes (iPPs) nucleated with a β-NA, N,N′-dicyclohexylterephthalamide (DCHT). With
the aid of fractionated crystallization, the possibility of DCHT to
form β-nuclei, i
β/i, is calculated to be reduced in PPR with ethylene inserted,
demonstrating fewer β-nuclei induced. As for growth, it is found
that the insertion of comonomer decreases the relative growth rate
of β-phase (G
β/G
α) and weakens the kinetic advantage of β-growth.
The study reveals that both i
β/i and G
β/G
α decrease with the insertion of comonomer. Fewer
β-nuclei induced by DCHT and the subsequent unfavorable β-growth
simultaneously contribute to the final decreased k
β. Our fundamental insight provides a more comprehensive
understanding of the decreased k
β as comonomer is inserted into the iPP chain and could have important
implications in the control of the polymorphism of polymers.