A Palladium-Containing Polyoxotungstate with Anisotropic Proton Conductivity
Lei Jia,
Yi-Xin Liu,
Xin-Xiong Li
et al.
Abstract:Here, a case of bilayer heterojunction Pd-containing polyoxotungstate (POW), connecting a Te 3 Pd 3 ring and an Anderson-like TeW 6 cluster, has been synthesized. The Anderson-like cluster is the first example in POW. The coordination of Pd in the ring with the S atom on the sulfo group breaks the traditional coordination configuration of Pd and O in polyoxometalates (POMs), enriching the structural types of Pd-containing POMs. In addition, the hybrid bilayer heterojunction structure at the molecular level not… Show more
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