“…Tin oxide (SnO 2 ), an n‐type semiconductor with a wide bandgap ( E g = 3.62 eV), is a key functional material, which has attracted a lot of interest as an excellent candidate for optoelectronic devices,1 gas sensors,2 transparent conducting electrodes,3 and catalyst supports 4. With specific morphologies, the hollow structures are more desirable because of their potential for encapsulation of large quantities of guest molecules or large‐sized guests within the empty core domain 5. For example, hollow SnO 2 microspheres offer enhancement in sensitivity to methanol, carbon monoxide, benzene, and water over compact chemical vapor deposition (CVD) films at high temperatures 6.…”