A Novel Non-Enzymatic Electrochemical Hydrogen Peroxide Sensor Based on a Metal-Organic Framework/Carbon Nanofiber Composite

Fu, Ying; Dai, Jiamu; Yan, Gao; Ke, Huizhen; Zhang, Wei

doi:10.3390/molecules23102552

Cited by 37 publications

(9 citation statements)

References 34 publications

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“…It has been found that some MOFs were applied as peroxidase mimetic with catalytic activities and nonenzymatic electrochemical hydrogen peroxide sensors. [22,45] Thus, in this work, it is proposed that H 2 O 2 was adsorbed in the pores of Ni-MOF and absorbed hydrogen peroxide was reduced into H 2 O along with the oxidation of 1,4-dihydropyrines to corresponding pyridines (Scheme 3).…”

Section: Introductionmentioning

confidence: 96%

Superparamagnetic core‐shell metal–organic framework Fe₃O₄@Ni‐MOF as efficient catalyst for oxidation of 1,4‐dihydropyridines using hydrogen peroxide

Janani

Abdoli‐Senejani

Isfahani

2021

Applied Organom Chemis

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A facile and efficient method was described for oxidation of some 3,5-diacyl or 3,5-diester 1,4-dihydropyridines using H 2 O 2 in the presence of superparamagnetic core-shell metal-organic framework Fe 3 O 4 @Ni-MOF. The Fe 3 O 4 @Ni-MOF has been obtained byStep-by-Step method in which magnetic Fe 3 O 4 magnetic nanoparticles were coated with Ni-MOF using a mercaptoacetic acid linker. The synthesized catalyst was characterized using thermogravimetric analysis, FT-IR spectroscopy, powder X-ray diffraction, field emission scanning electron microscopy and energy-dispersive X-ray analysis. The novel superparamagnetic core-shell metal-organic framework Fe 3 O 4 @Ni-MOF revealed high efficiency for oxidation of various 1,4-dihydropyridines using hydrogen peroxide. The Box-Behnken design matrix and the response surface method were applied to investigate the optimization of the reaction conditions. The conditions for optimal reaction yield and time were: amount of catalyst ≈17 mmol, temperature ≈78 C and amount of hydrogen peroxide ≈ 1 ml. A variety of 3,5-diacyl or 3,5-diester 1,4-dihydropyridines with different substituted functional groups have been converted to corresponding pyridines with good to excellent isolated yields using H 2 O 2 and Fe 3 O 4 @Ni-MOF. The catalyst was reused up to five times for the oxidation of 1,4-dihydropyridines without a significant loss in catalytic activity. The short reaction times, simplicity of method, good to excellent yields and reusability of catalyst were some advantages of the proposed procedure.

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Section: Introductionmentioning

confidence: 96%

Superparamagnetic core‐shell metal–organic framework Fe₃O₄@Ni‐MOF as efficient catalyst for oxidation of 1,4‐dihydropyridines using hydrogen peroxide

Janani

Abdoli‐Senejani

Isfahani

2021

Applied Organom Chemis

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“…It can be seen from Figure 10 that the ORR in 0.08 M H 2 O 2 /0.10 M KOH solution was shifted from the ORR in O 2 ‐saturated 0.10 M KOH solution because some of the H 2 O 2 decomposition according to Equation 5 and the E 0 cell value was calculated according to Equation 1 by the theoretical Gibbs free energy (▵G 0 ) from the appendix of Atkins′ Physical Chemistry, the calculated E 0 cell was 1.2471 V. This resulted to the ORR shift to higher positive potential. For hydrogen peroxide reduction reaction (HPRR), it occurred at the negative potential of around −0.15 to −1.00 V, following Equation [134–146]

true Δ normalG^{\circ} = nFE^{0}_{cell}

…”

Section: Resultsmentioning

confidence: 99%

“…For hydrogen peroxide reduction reaction (HPRR), it occurred at the negative potential of around À 0.15 to À 1.00 V, following Equation ( 6). [134][135][136][137][138][139][140][141][142][143][144][145][146] DG � ¼ nFE 0 cell (1) Where ~G°is the theoretical Gibbs free energy of H 2 O 2 decomposition (À 240.70 × 10 3 J), following the appendix of Atkins' Physical Chemistry), N is the number of moles of charges transferred, and F is the Faraday constant (96,500 C.mol À 1 ).…”

Section: Cyclic Voltammetry (Cv) and Chronoamperometry (Ca) Techniquesmentioning

confidence: 99%

Cu‐ and Fe‐Incorporated Manganese Oxides (Mn_xO_y) as Cathodic Catalysts for Hydrogen Peroxide Reduction (HPR) and Oxygen Reduction (OR) in Micro‐direct Methanol Fuel Cells

et al. 2022

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Improving manganese oxides as cathodic catalysts in direct methanol/hydrogen peroxide fuel cells by incorporation of Cu and Fe to promote oxygen reduction (OR) and hydrogen peroxide reduction (HPR) is reported. The Cu‐incorporated and Fe‐incorporated MnxOy were prepared by impregnation and solvothermal processes. From XRD, XPS, and XAS analyses, the obtained MnxOy consisted of MnO2 and mixed phases of Mn3O4 and Mn2O3 from impregnation and solvothermal methods, respectively. The Cu‐incorporated and Fe‐incorporated MnxOy included CuO and Fe2O3, respectively, through both methods. Addition of Cu and Fe decreased the BET surface area and increased the pore sizes as compared to the pristine MnO2. With the Fe : Mn molar ratio of 0.20 : 1, the Fe‐incorporated MnxOy from the solvothermal method presented the highest cathodic peaks under the cyclic voltammogram of HPR and OR at around 0.59 V of 11.59 mA cm−2 and −0.59 V of −12.33 mA cm−2, respectively. Compared to the Cu‐incorporated ones, the highest HPR peak at 0.68 V of 9.20 mA cm−2 and the highest OR peak at −0.59 V of −6.99 mA cm−2 were obtained from the Cu‐incorporated MnxOy prepared through the solvothermal method at the Cu : Mn molar ratio of 0.15 : 1. Incorporating Cu or Fe into MnO2 brought the improvement of electrocatalytic activity for HPR and OR. The Cu‐incorporated and Fe‐incorporated MnxOy from both methods showed a higher power density of μ‐DMFC than the pristine MnO2.

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Section: Introductionmentioning

confidence: 99%

Critical Review, Recent Updates on Zeolitic Imidazolate Framework‐67 (ZIF‐67) and Its Derivatives for Electrochemical Water Splitting

et al. 2022

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High surface area provides abundant active sites for catalytic reaction High Surface area Open crystal structure can exposes more interior atoms to provide more active sites Open crystal structure Organic linker acts as source of nitrogen source to improve the conductivity of overall matrix Organic linker Metal nanoparticles and metal complexes can be encapsulated inside MOFs to form guest@MOFs Tunable pore structure Figure 2.Advantages of the ZIF-67 for electrocatalytic application. The schematics of ZIF-67 was reproduced under the terms of the CC BY license. [468]

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A Novel Non-Enzymatic Electrochemical Hydrogen Peroxide Sensor Based on a Metal-Organic Framework/Carbon Nanofiber Composite

Cited by 37 publications

References 34 publications

Superparamagnetic core‐shell metal–organic framework Fe₃O₄@Ni‐MOF as efficient catalyst for oxidation of 1,4‐dihydropyridines using hydrogen peroxide

Superparamagnetic core‐shell metal–organic framework Fe₃O₄@Ni‐MOF as efficient catalyst for oxidation of 1,4‐dihydropyridines using hydrogen peroxide

Cu‐ and Fe‐Incorporated Manganese Oxides (Mn_xO_y) as Cathodic Catalysts for Hydrogen Peroxide Reduction (HPR) and Oxygen Reduction (OR) in Micro‐direct Methanol Fuel Cells

Critical Review, Recent Updates on Zeolitic Imidazolate Framework‐67 (ZIF‐67) and Its Derivatives for Electrochemical Water Splitting

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A Novel Non-Enzymatic Electrochemical Hydrogen Peroxide Sensor Based on a Metal-Organic Framework/Carbon Nanofiber Composite

Cited by 37 publications

References 34 publications

Superparamagnetic core‐shell metal–organic framework Fe3O4@Ni‐MOF as efficient catalyst for oxidation of 1,4‐dihydropyridines using hydrogen peroxide

Superparamagnetic core‐shell metal–organic framework Fe3O4@Ni‐MOF as efficient catalyst for oxidation of 1,4‐dihydropyridines using hydrogen peroxide

Cu‐ and Fe‐Incorporated Manganese Oxides (MnxOy) as Cathodic Catalysts for Hydrogen Peroxide Reduction (HPR) and Oxygen Reduction (OR) in Micro‐direct Methanol Fuel Cells

Critical Review, Recent Updates on Zeolitic Imidazolate Framework‐67 (ZIF‐67) and Its Derivatives for Electrochemical Water Splitting

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Superparamagnetic core‐shell metal–organic framework Fe₃O₄@Ni‐MOF as efficient catalyst for oxidation of 1,4‐dihydropyridines using hydrogen peroxide

Superparamagnetic core‐shell metal–organic framework Fe₃O₄@Ni‐MOF as efficient catalyst for oxidation of 1,4‐dihydropyridines using hydrogen peroxide

Cu‐ and Fe‐Incorporated Manganese Oxides (Mn_xO_y) as Cathodic Catalysts for Hydrogen Peroxide Reduction (HPR) and Oxygen Reduction (OR) in Micro‐direct Methanol Fuel Cells