Abstract:A major part of the world's remaining oil reserves is in fractured carbonate reservoirs, which are dual-porosity (fracture-matrix) or multiporosity (fracture/vug/matrix) in nature. Fractured reservoirs suffer from poor recovery, high water cut, and generally low performance. They are modeled commonly by use of a dual-porosity approach, which assumes that the high-permeability fractures are mobile and low-permeability matrix is immobile. A single transfer function models the rate at which hydrocarbons migrate f… Show more
“…The most widely used are the Multi-Rate Mass Transfer (MRMT) and Continuous Time Random Walk (CTRW). MRMT is a non-local in time continuous formulation that simulates mass transfer between a mobile and multiple immobile regions by diffusive or first-order mass transfer terms (Benson and Meerschaert, 2009;Carrera et al, 1998;Donado et al, 2009;Fernandez-Garcia and Sanchez-Vila, 2015;Geiger et al, 2013;Gouze et al, 2008;Haggerty and Gorelick, 1995;Haggerty et al, 2000;Roth and Jury, 1993;Wang et al, 2005;Willmann et al, 2010;Zhang et al, 2007). Models similar to MRMT exist for diffusion from a fracture into the matrix of the rock (Cvetkovic et al, 1999;Gerke and van Genuchten, 1996;Grisak and Pickens, 1980;MaĆoszewski and Zuber, 1985;Moreno and Neretnieks, 1993;Shapiro, 2001).…”
Results of reactive transport laboratory experiments often suggest that pore scale heterogeneity induces localization of reactions (the generation of local micro environments favoring reactions that would not occur in a well-mixed Representative Elementary Volume, REV). Multi-Rate Mass Transfer (MRMT), which has been employed to reproduce hydrodynamic heterogeneity, may also be used to simulate geochemical localization. We extended the Water Mixing Approach (WMA) designed for single porosity media, to simulate chemical reactions caused by the mixing of mobile and immobile zones. The method is termed Multi-Rate Water Mixing (MRWM). The MRWM approach was employed to simulate laboratory experiments of CO2-rich brine transport through carbonate rich samples (Luquot et al., 2016, in this issue). Chemical heterogeneity in space was reproduced by varying the mineral assemblages in immobile regions. This enabled us to reproduce the generally low pH environment while allowing for high pH local zones required for the localized precipitation of kaolinite, which has been observed in reality, but cannot be modeled with conventional reactive transport formulations. The resulting model is very rich, in that it can reproduce a broad range of pore scale processes in a Darcy scale model, and complex, in that the interaction between chemical kinetics and immobile zones physical parameters is non-trivial.Peer ReviewedPostprint (author's final draft
“…The most widely used are the Multi-Rate Mass Transfer (MRMT) and Continuous Time Random Walk (CTRW). MRMT is a non-local in time continuous formulation that simulates mass transfer between a mobile and multiple immobile regions by diffusive or first-order mass transfer terms (Benson and Meerschaert, 2009;Carrera et al, 1998;Donado et al, 2009;Fernandez-Garcia and Sanchez-Vila, 2015;Geiger et al, 2013;Gouze et al, 2008;Haggerty and Gorelick, 1995;Haggerty et al, 2000;Roth and Jury, 1993;Wang et al, 2005;Willmann et al, 2010;Zhang et al, 2007). Models similar to MRMT exist for diffusion from a fracture into the matrix of the rock (Cvetkovic et al, 1999;Gerke and van Genuchten, 1996;Grisak and Pickens, 1980;MaĆoszewski and Zuber, 1985;Moreno and Neretnieks, 1993;Shapiro, 2001).…”
Results of reactive transport laboratory experiments often suggest that pore scale heterogeneity induces localization of reactions (the generation of local micro environments favoring reactions that would not occur in a well-mixed Representative Elementary Volume, REV). Multi-Rate Mass Transfer (MRMT), which has been employed to reproduce hydrodynamic heterogeneity, may also be used to simulate geochemical localization. We extended the Water Mixing Approach (WMA) designed for single porosity media, to simulate chemical reactions caused by the mixing of mobile and immobile zones. The method is termed Multi-Rate Water Mixing (MRWM). The MRWM approach was employed to simulate laboratory experiments of CO2-rich brine transport through carbonate rich samples (Luquot et al., 2016, in this issue). Chemical heterogeneity in space was reproduced by varying the mineral assemblages in immobile regions. This enabled us to reproduce the generally low pH environment while allowing for high pH local zones required for the localized precipitation of kaolinite, which has been observed in reality, but cannot be modeled with conventional reactive transport formulations. The resulting model is very rich, in that it can reproduce a broad range of pore scale processes in a Darcy scale model, and complex, in that the interaction between chemical kinetics and immobile zones physical parameters is non-trivial.Peer ReviewedPostprint (author's final draft
“…First, the implementation of the LM-L 2 method is tested by comparing the obtained results to 2D benchmark results presented by Flemisch et al [20]. Benchmark 1, which was first introduced by Geiger et al [24], is chosen as a representative example for this study. Emphasis is placed on the validation of the presented method with reference results from Geiger et al [24], Flemisch et al [20], while results of alternative approaches can be found in the listed references.…”
This work presents a modeling approach for single-phase flow in 3D fractured porous media with non-conforming meshes. To this end, a Lagrange multiplier method is combined with a parallel L 2 -projection variational transfer approach. This Lagrange multiplier method enables the use of non-conforming meshes and depicts the variable coupling between fracture and matrix domain. The L 2 -projection variational transfer allows general, accurate, and parallel projection of variables between non-conforming meshes (i.e. between fracture and matrix domain). Comparisons of simulations with 2D benchmarks show good agreement, and the method is further validated on 3D fracture networks by comparing it to results from conforming mesh simulations which were used as a reference. Application to realistic fracture networks with hundreds of fractures is demonstrated. Mesh size and mesh convergence are investigated for benchmark cases and 3D fracture network applications. Results demonstrate that the Lagrange multiplier method, in combination with the L 2 -projection method, is capable of modeling single-phase flow through realistic 3D fracture networks.
“…Having a pure calcium carbonate system with no chemical heterogeneity, the partitioning of the porous medium is only due to the physical heterogeneity at pore scale (fracture/matrix), and therefore, no localization of reactions is assumed. We consider one immobile zone only, to align the formulation with the timeâdependent singleârate mass transfer model as opposed to multiple rate mass transfer model where multiple mass transfer processes occur simultaneously in a porous medium (see, e.g., FernandezâGarcia & SanchezâVila, ; Geiger et al, ; Maier et al, ; SolerâSagarra et al, ; Tecklenburg et al, ). As such equation (3) can be rewritten as …”
Section: Simplified Co2 Reaction With Calcium Carbonatementioning
confidence: 99%
“…Having a pure calcium carbonate system with no chemical heterogeneity, the partitioning of the porous medium is only due to the physical heterogeneity at pore scale (fracture/matrix), and therefore, no localization of reactions is assumed. We consider one immobile zone only, to align the formulation with the time-dependent singlerate mass transfer model as opposed to multiple rate mass transfer model where multiple mass transfer processes occur simultaneously in a porous medium (see, e.g., Fernandez-Garcia & Sanchez-Vila, 2015; Geiger et al, 2013;Maier et al, 2013;Soler-Sagarra et al, 2016;Tecklenburg et al, 2016). As such equation (3) can be rewritten as…”
Section: Simplified Co 2 Reaction With Calcium Carbonatementioning
The objective of this paper is to study the impact of immobile water, its fraction, and its mass transfer with the flowing region on efficiency of CO2 dissolution in aquifers with an immobile water zone. A continuum scale code is developed with underlying assumptions of spatially homogeneous and temporally invariable partitioning fraction of the porous media, firstâorder mass transfer between the mobile and immobile zones, and simplified reaction of CO2 aqueous solution with calcium carbonate rock. Using ranges of values for Damköhler number (Da), fraction of the total pore volume, and mass transfer coefficient rate (α), 96 simulations are conducted. It is shown that due to a lower intensity of reaction in the mobile region, intermediate values of α serve as a threshold below which the mass transfer coefficient is not affecting the overall CO2 storage and above which overall CO2 storage increases as a function of mass transfer coefficient. Additionally, we found that (i) when α is high and geochemistry is intensive (high Da), the overall CO2 storage decreases with increase in fraction of mobile water. This is because CO2 storage through consumption of rock in immobile water with higher geochemistry is reduced. (ii) When α is high but Da is low, the system is effectively a single porosity medium with no chemistryâinfluenced discrimination between mobile and immobile zones, and therefore, overall CO2 storage increases with fraction of mobile water. (iii) When α is low, the magnitude of Da does not influence the overall CO2 storage.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citationsâcitations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.