Abstract:A manganese complex with mixed ligands, [Mn(2,2′-biim)2(4,4′-bipy)] n[Mn(2,2′-biim)3]2 n6 n(ClO4)•8 nH2O (2,2′-biim = 2,2′-biimidazole; 4,4′-bipy = 4,4′-bipyridine), has been obtained by a hydrothermal procedure and its structure determined by single-crystal X-ray crystallography. A two-dimensional (2-D) supramolecular layer is established through hydrogen-bonding interactions. Solid-state photoluminescence measurement reveals that this complex shows a blue light emission. Solid-state diffuse reflectance deter… Show more
Two unreported metal–organic frameworks [Cu(6-Me-2,3-pydc)(1,10-phen)·7H2O]n (namely Cu-MOF) and [Mn2(2,2′-bca)2(H2O)2]n (namely Mn-MOF) were synthesized and characterized. Cu-MOF and Mn-MOF all can form a three-dimensional structure.
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