Assessing uncertainty in decision-making is a major challenge for decision makers (DMs) and the q-rung orthopair fuzzy set (q-ROFS), as the direct extension of intuitionistic fuzzy set (IFS) and pythagorean fuzzy set (PFS) play a crucial role in this aspect. The complex q-rung orthopair fuzzy set (Cq-ROFS) is a strong tool to deal with imprecision, vagueness and fuzziness by expanding the scope of membership degree (MD) and non-membership degree (NMD) of q-ROFS from real to complex unit disc. In this paper, we develop some new Cq-ROF Hamacher aggregation operators (AOs), i.e., the Cq-ROF Hamacher weighted averaging (Cq-ROFHWA) operator, the Cq-ROFH weighted geometric (Cq-ROFHWG) operator, the Cq-ROFH ordered weighted averaging (Cq-ROFHOWA) operator and the Cq-ROFH ordered weighted geometric (Cq-ROFHOWG) operator. Subsequently, we establish a novel Cq-ROF graph framework based on the Hamacher operator called Cq-ROFH graphs (Cq-ROFHGs) and evaluate its energy and Randić energy. In particular, we compute the energy of a splitting Cq-ROFHG and shadow Cq-ROFHG. Further, we describe the notions of Cq-ROFH digraphs (Cq-ROFHDGs). Moreover, an algorithm is given to solve multiple attribute group decision making (MAGDM) problems and the main steps are discussed clearly. Finally, a numerical instance related to the facade clothing systems (FCS) selection is presented to show the affectiveness of the developed concepts in decision-making circumstances. In order to verify the effectiveness of our proposed scheme, a comparative analysis with previous approaches is provided.