A novel Fe3O4–SnO2–graphene ternary nanocomposite as an anode material for lithium-ion batteries

Lian, Peichao; Liang, Shuzhao; Zhu, Xuefeng; Yang, Weishen; Wang, Haihui

doi:10.1016/j.electacta.2011.08.088

Cited by 71 publications

(30 citation statements)

References 39 publications

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“…Most notably, the GCS/FO-NC-D electrode also has excellent cycle stability and good Coulombic efficiency even at a high current density of 1000 mA g -1 (Fig 7a). Its initial discharge sepcific capacity is up to 1385.2 mAh g -1 , which is almost 4 times the capacity of a commercial graphite anode (372 mAh/g), and is the highest rate capability compared with those reported in the literature [27][28][29][30][31][50][51][52][53]. And it still exhibits a high reversible capacity (750 mAh g -1 ) after 1400 discharge/charge cycles.…”

Section: Resultssupporting

confidence: 51%

“…2h) of an individual Fe3O4 nanoparticle displays its superlattice structure with a larger lattice spacing of 0.98 nm [41]. and 43.1° [22][23][24][25][26][27][28][29][30][31] and the diffraction peaks of β-SiC (PDF#49-1623) with a cubic crystal system [42]. The broad peak indicates that its structure has a high degree of disorder.…”

Section: Resultsmentioning

confidence: 99%

“…The composite anode materials of graphene and Fe3O4 have been recently explored and show enhanced high capacity and excellent cycling performance of LIBs [25][26][27][28][29][30][31]. However, utilization of the active materials.…”

Section: Introductionmentioning

confidence: 99%

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Graphene-like carbon sheet/Fe3O4 nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries

Zhang

et al. 2017

Electrochimica Acta

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like carbon sheet/Fe3O4 nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries, Electrochimica Acta http://dx.doi.org/10. 1016/j.electacta.2017.02.130 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. . Even at a high current density (1000 mA g -1 ), it still exhibits a high reversible capacity (750 mAh g -1 ) after 1400 discharge/charge cycles. More importantly, the removal efficiency of chemical oxygen demand of SPBL is up to 83.4% during the synthesis process, which reduce its load to environment and synthetic cost of carbon-based nanocomposite anodes.

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Section: Resultssupporting

confidence: 51%

Section: Resultsmentioning

confidence: 99%

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Graphene-like carbon sheet/Fe3O4 nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries

Zhang

et al. 2017

Electrochimica Acta

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“…At the same time, previously reported graphene-containing alloy (e.g., Sn, [ 144 ] SnO 2 [145][146][147][148][149] or Si [150][151][152][153] ), conversion (e.g., Fe 3 O 4 , [154][155][156][157] Co 3 O 4 [158][159][160][161] or CuO [162][163][164] ) and insertion (e.g., TiO 2 [165][166][167][168] or LTO [169][170][171] ) hybrids were further improved. Interestingly, some appealing approaches, such as the use of ternary hybrids (e.g., RGO/SnO 2 /Fe 3 O 4 [ 172 ] or RGO/CNT/ Sn [ 173 ] ), porous 3D (e.g., RGO/Fe 3 O 4 [ 174,175 ] ) and hollow architectures (e.g., RGO/Fe 3 O 4 [ 176 ] and RGO/TiO 2 [ 168 ] ), were introduced. In all these cases, however, only modest improvements (especially in terms of cycling stability) were observed with respect to the reports published few years before.…”

mentioning

confidence: 99%

“…In all these cases, however, only modest improvements (especially in terms of cycling stability) were observed with respect to the reports published few years before. Although several publications reported the active material mass loadings, [ 58,60,65,129,130,132,138,142,147,168,172,[177][178][179][180] as well as the tap density of the active material [ 57 ] and the density of the electrode, [ 63 ] no considerations about volumetric capacity were made. Some progression on composite anodes based on graphene and germanium (i.e., alloy material), MFe 2 O 4 (M = Co, Ni, Cu) and M x S y (M = Sn, Sb, In) were reported in 2012.…”

mentioning

confidence: 99%

Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes

et al. 2016

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that its extraordinary properties would enable revolutionary new technologies, which gave birth to the "graphene era". [ 3,4 ] Relying on this scenario, in 2013, the European Union launched the ¤1 billion "Graphene Flagship" project aimed to investigate the properties of this new form of carbon for various applications (e.g., electronics, sensors and energy storage devices), with the ambitious goal of guiding graphene from laboratories to commercial applications within a decade. [ 5,6 ] In the same period, the Chinese Government set up a similar investment to mass-produce graphene as thin fi lms (e.g., for touchscreen electrodes) and platelets (e.g., for use in batteries). [ 6 ] In the following years, hundreds of patents, mainly focused on manufacturing and application in energy storage, were fi led and the worldwide production of graphene and graphene-containing materials rapidly increased. Although a few Chinese industries claimed to already use graphene-containing materials for smartphone production, no revolutionary practical application relying on graphene has been yet developed. [ 6 ] Specifi cally with respect to the battery fi eld, a close analysis of the scientifi c literature reveals a struggle to meet the ambitious initial targets. A potential loss of focus from the fi nal application caused by hype and ease of publication on such a novel matter, together with the delivery of very misleading information [ 7,8 ] and erroneous statements [ 7 ] concerning the use of graphene in batteries are emerging as possible reasons of the ineffective graphene-era outburst. In this progress report, we do not focus on production and classifi cation of graphene and graphene-containing materials, which were already well reported in the past years. [ 3,[9][10][11] In contrast, due to the lack of an exhaustive analysis of the progression of the use of such materials in lithium-ion battery (LIB) anodes, we report here a critical evaluation of the most prominent research papers published from 2008 until the end of 2015. As shown in Figure 1 , three different stages of the graphene research in LIB anodes can be distinguished: a fi rst stationary phase between 2008 and 2010 where the lithium-ion storage properties of different graphene and graphene-containing materials were preliminarily explored, a second exponential stage, spanning from 2010 to 2014, where graphene and graphene-containing anode materials were broadly developed and investigated, and fi nally, a third phase, (i.e., starting from 2015), where the research seems to have approached a plateau. After Used as a bare active material or component in hybrids, graphene has been the subject of numerous studies in recent years. Indeed, from the fi rst report that appeared in late July 2008, almost 1600 papers were published as of the end 2015 that investigated the properties of graphene as an anode material for lithium-ion batteries. Although an impressive amount of data has been collected, a real advance in the fi eld still seems to be missing. In this framework, atten...

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Controlled Growth of Porous α‐Fe₂O₃ Branches on β‐MnO₂ Nanorods for Excellent Performance in Lithium‐Ion Batteries

Chen

et al. 2013

Adv Funct Materials

184

130

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Hierarchical nanocomposites rationally designed in component and structure, are highly desirable for the development of lithium‐ion batteries, because they can take full advantages of different components and various structures to achieve superior electrochemical properties. Here, the branched nanocomposite with β‐MnO2 nanorods as the back‐bone and porous α‐Fe2O3 nanorods as the branches are synthesized by a high‐temperature annealing of FeOOH epitaxially grown on the β‐MnO2 nanorods. Since the β‐MnO2 nanorods grow along the four‐fold axis, the as‐produced branches of FeOOH and α‐Fe2O3 are aligned on their side in a nearly four‐fold symmetry. This synthetic process for the branched nanorods built by β‐MnO2/α‐Fe2O3 is characterized. The branched nanorods of β‐MnO2/α‐Fe2O3 present an excellent lithium‐storage performance. They exhibit a reversible specific capacity of 1028 mAh g−1 at a current density of 1000 mA g−1 up to 200 cycles, much higher than the building blocks alone. Even at 4000 mA g−1, the reversible capacity of the branched nanorods could be kept at 881 mAh g−1. The outstanding performances of the branched nanorods are attributed to the synergistic effect of different components and the hierarchical structure of the composite. The disclosure of the correlation between the electrochemical properties and the structure/component of the nanocomposites, would greatly benefit the rational design of the high‐performance nanocomposites for lithium ion batteries, in the future.

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A novel Fe3O4–SnO2–graphene ternary nanocomposite as an anode material for lithium-ion batteries

Cited by 71 publications

References 39 publications

Graphene-like carbon sheet/Fe3O4 nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries

Graphene-like carbon sheet/Fe3O4 nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries

Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes

Controlled Growth of Porous α‐Fe₂O₃ Branches on β‐MnO₂ Nanorods for Excellent Performance in Lithium‐Ion Batteries

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A novel Fe3O4–SnO2–graphene ternary nanocomposite as an anode material for lithium-ion batteries

Cited by 71 publications

References 39 publications

Graphene-like carbon sheet/Fe3O4 nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries

Graphene-like carbon sheet/Fe3O4 nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries

Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes

Controlled Growth of Porous α‐Fe2O3 Branches on β‐MnO2 Nanorods for Excellent Performance in Lithium‐Ion Batteries

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Controlled Growth of Porous α‐Fe₂O₃ Branches on β‐MnO₂ Nanorods for Excellent Performance in Lithium‐Ion Batteries