In order to solve the problem that the traditional e-commerce logistic distribution path optimization algorithm takes a long time to find the optimal path, this paper presents the best ways for exporting based on RFID and sensor technology. First, the integration algorithm is used to divide the logistic area; then, the purpose of various goals to improve the performance of the export consists of five things: measuring weight, measuring time, measuring the importance of customers, window measuring time, and general measurement method. Finally, determine the weight distribution target and find ways to better the target according to the differences in e-commerce logistics to improve the efficiency of e-commerce logistic distribution methods. Experimental results show that the optimal time to find the optimal method is less than 2 minutes, while the custom algorithm takes 3 minutes to find the optimal method. Conclusion. The logistic distribution optimization algorithm based on RFID and sensor technology takes less time to find a better way than the traditional process and can meet the needs of e-commerce logistic distribution layer standard optimization.