A novel electrochemical sensor for metoprolol analysis based on glutardialdehyde–zinc oxide modified boron doped diamond electrode

Koçak, Berna; İpek, Yeliz; Keçeci, Ali

doi:10.1016/j.diamond.2022.109558

Cited by 7 publications

(8 citation statements)

References 33 publications

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“…Furthermore, the reproducibility of the estimated method was checked by fabricating five various Cr/ZnO-NPs/CPE sensors using the same conditions mentioned in heading 2.6. All the manufactured sensors produced virtually similar values, implying good reproducibility, demonstrated by a good RSD of 1.77 . The Cr/ZnO-NPs/CPE electrodes’ day-to-day stability was estimated by determining the oxidation peak current at the concentration (0.04 μM) of ETF on the Cr/ZnO-NPs/CPE over a period of 25 days.…”

Section: Resultsmentioning

confidence: 96%

“…A comparison was made between the proposed method and the published potentiometric method. , As shown in Table , the computed values of Student’s t -test and F -test were lower than the tabulated ones, showing no notable change in accuracy and precision of the two methods. A one-way ANOVA with a 95% confidence interval ( P = 0.05) was conducted to compare the recovery percentage for the developed electrodes and the reported potentiometric technique.…”

Section: Resultsmentioning

confidence: 96%

“…All the manufactured sensors produced virtually similar values, implying good reproducibility, demonstrated by a good RSD of 1.77. 43 The Cr/ZnO-NPs/CPE electrodes' day-to-day stability was estimated by determining the oxidation peak current at the concentration (0.04 μM) of ETF on the Cr/ ZnO-NPs/CPE over a period of 25 days. Furthermore, the Cr/ ZnO-NPs/CPE electrodes were shown to have long-term stability after being kept in the refrigerator temperature for 25 days.…”

Section: Nf Log Omentioning

confidence: 99%

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Green Prospective Approach of Chromium Zinc Oxide Nanoparticles for Highly Ultrasensitive Electrochemical Detection of Anti-hypotensive Medication in Various Matrices

Otaif,

Fouad,

Rashed

et al. 2023

ACS Omega

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A highly ultrasensitive sensor that relied on Cr/ZnO-NPs was developed to detect etilefrine hydrochloride (ETF) in different matrices via a particular green voltammetric technique. The X-ray diffraction pattern showed the nanomaterials of the polycrystalline hexagonal structure. The energy-dispersive X-ray spectrum approved the presence of Cr 3+ inside the host zinc oxide framework. The morphological and topological characteristics were visualized using transmission electron microscopy and atomic force microscopy micrographs describing the nanoparticles in spherical-like shape with large-surface area. The energy gap (E g ) was evaluated from transmittance (T %) and reflectance (R %) spectra within the visible region. The optimization study indicated that the Cr/ZnO-NP/CPE sensor has high sensitivity, thanks to the distinctive physical and chemical properties of the fabricated electrode. A new approach showed a great selectivity for determining ETF in different matrices in the presence of other interferents like levodopa. Under optimal circumstances, the squarewave voltammetry revealed a linear response to ETF from 0.01 to 10 μmol L −1 (r = 0.9996) with quantification and detection limits of 9.11 and 2.97 nmol L −1 , respectively. Finally, the proposed approach was effectively applied to estimate ETF in pharmaceutical dosage forms and biological fluids using simple, accurate, and selective electrochemical electrode. The greenness profile assessment of the developed method was performed using the Eco-Scale and green analytical procedure index. These tools indicated that the proposed method is an eco-friendly technique for the determination of ETF in different matrices.

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Section: Resultsmentioning

confidence: 96%

Section: Resultsmentioning

confidence: 96%

Section: Nf Log Omentioning

confidence: 99%

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Green Prospective Approach of Chromium Zinc Oxide Nanoparticles for Highly Ultrasensitive Electrochemical Detection of Anti-hypotensive Medication in Various Matrices

Otaif,

Fouad,

Rashed

et al. 2023

ACS Omega

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“…Regarding the electrochemical characterization, the modification of the electrode surface will affect the electroactive surface area and conductivity. [23,37] Therefore, in order to show the change in the electrode surface area and conductivity of the CuO-GA 2 modified BDD, CVs were taken at different scan rates (25-500 mV s À 1 ) on the BDDE and CuO-GA 2 /BDDE in 1 mM K 3 Fe(CN) 6 as a probe redox system at different scan rates (Figure 5).…”

Section: Comparison Of Electrodes and Characterization Of Cuo-ga 2 / ...mentioning

confidence: 99%

“…[22] In addition, GA 2 has been successfully used as a chemical binder in the electrochemical analysis of the blood pressure medications metoprolol and nebivolol. [23,24] The electrocatalytic properties of the electrode are analyzed with electroanalytical sensing. Nanomaterials are preferred for increasing the electrocatalytic properties because of several characteristics they possess, including having a: large surface area, suitable adsorption capacity, large number of surface active sites, and high catalytic efficiency.…”

Section: Introductionmentioning

confidence: 99%

A Selective and Sensitive Electrochemical Sensor for Pyridoxine Hydrochloride (Vitamin B6) in Pharmaceutic Tablet

Koçak

2023

ChemistrySelect

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In this study, a copper (II) oxide‐glutardialdehyde modified boron doped diamond electrode was used as a sensor for the electroanalysis of pyridoxine hydrochloride (vitamin B6) for the first time. A copper oxide‐glutardialdehyde modified boron doped diamond electrode (CuO‐GA2/BDDE) was prepared by a simple drop casting method on boron diamond electrode (BDDE) by suspending CuO with glutardialdehyde (CuO‐GA2). The electrochemical behavior of vitamin B6 was examined using cyclic voltammetry (CV) and its electrochemical determination was found by differential pulse voltammetry (DPV). Under optimum experimental conditions, the linear working range of vitamin B6 on CuO‐GA2/BDDE via the DPV method was calculated as 5.96×10−6–3.75×10−4 mol.L−1. The limit of detection (LOD) was calculated as 1.99×10−7 mol.L−1. In order to demonstrate the selectivity of the method improved for the quantitative determination of vitamin B6 on the CuO‐GA2/BDDE, the interference effect of some cations (Zn2+, Cu2+, Pb2+) and anions (NO3−, Cl−) was investigated via the DPV method. The improved electrode was successfully used for the electroanalysis of vitamin B6 in a tablet sample of the commercial Tribeksol® (deva) (250/250/1 mg B1+B6+B12).

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Sensitive electrochemical detection of doping agent metoprolol between athletes via copper phthalocyanine-modified graphitic carbon nitride electrode: a versatile approach for doping surveillance in food products and biological fluids

Li,

Bai,

Zhang

2023

Food Measure

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A novel electrochemical sensor for metoprolol analysis based on glutardialdehyde–zinc oxide modified boron doped diamond electrode

Cited by 7 publications

References 33 publications

Green Prospective Approach of Chromium Zinc Oxide Nanoparticles for Highly Ultrasensitive Electrochemical Detection of Anti-hypotensive Medication in Various Matrices

Green Prospective Approach of Chromium Zinc Oxide Nanoparticles for Highly Ultrasensitive Electrochemical Detection of Anti-hypotensive Medication in Various Matrices

A Selective and Sensitive Electrochemical Sensor for Pyridoxine Hydrochloride (Vitamin B6) in Pharmaceutic Tablet

Sensitive electrochemical detection of doping agent metoprolol between athletes via copper phthalocyanine-modified graphitic carbon nitride electrode: a versatile approach for doping surveillance in food products and biological fluids

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