2014
DOI: 10.1039/c4ra07552h
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A novel colorimetric and fluorogenic chemosensor for selective detection of Cu2+ ions in mixed aqueous media

Abstract: A novel and easy-to-synthesize chemosensor (L) was developed for the selective sensing of Cu2+ ions in mixed aqueous medium.

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Cited by 50 publications
(11 citation statements)
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“…The 1 H‐NMR spectra of 1 showed considerable variation in presence of Cu 2+ in DMSO‐d 6 solvent (Figure ). The downfield value of H a (of –OH) in 1 was due to the intra‐molecular hydrogen bond between the imine‐N atoms of 1 with H a forming a six‐membered transition state . On addition of Cu 2+ ions, the intramolecular hydrogen bonding got disturbed.…”
Section: Resultssupporting
confidence: 73%
“…The 1 H‐NMR spectra of 1 showed considerable variation in presence of Cu 2+ in DMSO‐d 6 solvent (Figure ). The downfield value of H a (of –OH) in 1 was due to the intra‐molecular hydrogen bond between the imine‐N atoms of 1 with H a forming a six‐membered transition state . On addition of Cu 2+ ions, the intramolecular hydrogen bonding got disturbed.…”
Section: Resultssupporting
confidence: 73%
“…The sensor exhibit near‐infrared (NIR) fluorescence for Cu 2+ ion. Yadav et al . also synthesized one fluoro chemosensor for Cu 2+ ions in mixed organic‐water media.…”
Section: Detection Of Copper By Sensing Technologysupporting
confidence: 71%
“…47 The downeld value of H a (of -OH) at d ¼ 14.86 ppm in CTPE was due to the intramolecular hydrogen bond between the imine-N atom of CTPE with H a forming a six-membered transition state. 48 On addition of Cu 2+ ion, the intramolecular hydrogen bonding was disturbed. 49 As Cu 2+ gradually increased, the proton signal of H a almost disappeared.…”
mentioning
confidence: 99%