2009
DOI: 10.1016/j.aca.2009.09.004
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A novel cobalt hexacyanoferrate nanocomposite on CNT scaffold by seed medium and application for biosensor

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Cited by 36 publications
(17 citation statements)
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References 52 publications
(61 reference statements)
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“…9A(b) inset) with current sensitivity of 19.7 lA/mM, which is about 20 times sensitive over the sol-gel modified Ni-NCFe ($1 lA/mM) [9]. Such an enhanced catalytic activity for the GCE/ Ni-NCFe@f-MWCNT electrode could originate from a combination of an increased availability of inner-walls-bound Ni-NCFe sites within the f-MWCNT and macro-molecular Ni-NCFe units precipitated on the CNT surface that is clearly distinct from the traditional ex-situ preparation approach [11,12,[26][27][28][29], where the catalyst particles were assembled/adsorbed exclusively on the external surface of the CNT. Extended amperometric detection methods as in Fig.…”
Section: Electrocatalytic and Amperometric Sensing Behaviorsmentioning
confidence: 94%
“…9A(b) inset) with current sensitivity of 19.7 lA/mM, which is about 20 times sensitive over the sol-gel modified Ni-NCFe ($1 lA/mM) [9]. Such an enhanced catalytic activity for the GCE/ Ni-NCFe@f-MWCNT electrode could originate from a combination of an increased availability of inner-walls-bound Ni-NCFe sites within the f-MWCNT and macro-molecular Ni-NCFe units precipitated on the CNT surface that is clearly distinct from the traditional ex-situ preparation approach [11,12,[26][27][28][29], where the catalyst particles were assembled/adsorbed exclusively on the external surface of the CNT. Extended amperometric detection methods as in Fig.…”
Section: Electrocatalytic and Amperometric Sensing Behaviorsmentioning
confidence: 94%
“…As a result, metal hexacyanoferrates nanoparticles modified electrodes have also been investigated [12][13][14][15][16][17][18][19][20][21][22][23][24]. Baioni et al [12,13] synthesized copper hexacyanoferrate nanoparticles and the nanoparticles were immobilized on the surface of ITO electrodes by the method of self-assembled layers.…”
Section: Introductionmentioning
confidence: 98%
“…With high mechanical strength, excellent conductivity and antifouling properties, multiwalled carbon nanotubes (MWCNTs) have been immensely used in glucose sensors for GOx immobilization [2]. Some of the recently reported MWCNT matrices for GOx immobilization are ionic liquid n-octylpyridinum hexafluorophosphate dispersed MWCNT [3], MWCNT/gold nanoparticlesTeflon composites [4], Chitosan dispersed MWCNT [5], gold nanoparticles/thiol group functionalized MWCNT/Chitosan-ionic liquid [6], cobalt hexacyanoferrate nanoparticles/gold nanoparticles (seed)/ MWCNT composites [7], crystalline gold nanoparticles modified MWCNT [8], platinum nanoparticle/MWCNT composites [9], nitrogen doped MWCNT [10] and polymerized ionic liquid-wrapped MWCNT [11]. The inclusion of MWCNT into the immobilization matrix leads to the high sensitivity and good stability of the immobilized enzyme [3].…”
Section: Introductionmentioning
confidence: 99%