A Novel Boron Oxide Organic Open‐Framework Compound: B₆O₉(en)₂@(H₂en)Cl₂

Abstract

A new boron oxide organic open‐framework compound with (H2en)Cl2 as a template was synthesized solvothermally and characterized by various techniques such as elemental analysis, IR spectroscopy, X‐ray diffraction, thermogravimetric analysis, and luminescence. The framework is built up from neutral [B6O9] layers linked by ethylenediamine molecules through coordinative B–N bonds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

AlB3O6(OH)·0.5(C2H10N2): An organically templated aluminoborate with hnb-layer structure

“…Recently, hydrothermal methods were proposed for the formation of borate materials, which allows the use of organic additives (organic amines [6][7][8][9][10][11][12][13][14][15] or transition metalcomplex [16][17][18][19]) as "template". It is noteworthy that the presence of the organic species can further enhance the possibilities for synthesizing novel borates.…”