A Novel 3D Metal Coordination Polymer Based on Tetranuclear Zinc Cluster Building Blocks: Syntheses, Structures and Photoluminescent Property

The crystal structure of (2E,2′E)-,2,2′-bis[1-(2-pyrazinyl)ethylidene]carbonimidic dihydrazide, C13H15N9

“…Therefore, the search for highly efficient and safe antitumor agents has become more urgent than ever before. The aminoguanidine class [6][7][8][9][10][11], a diverse group of bioactive compounds used in the treatment of a broad range of diseases from bacterial infections to cancer and diabetes are already approved for human use. The asymmetric unit of the title structure contains one title molecule.…”

Crystal structure of poly[triaqua-bis(μ3-3,3′-((5-carboxylato-1,3-phenylene)bis(oxy))dibenzoato)-tris(1,10-phenanthroline)cobalt(II)], C78H46N6O20Co3

“…Three benzene rings can support the space well and form functional complexes more powerfully, and the existence of oxygen ion give them amount of space to rotate and twist, to provide different coordinations. In this project we used 1,10phenanthroline as auxiliary ligands [3,4] to sythesize the title complexes.…”

A new porous heterometallic metal‐organic framework for gas adsorption and luminescence sensing

“…The intrinsic geometrical features of SBUs can help us direct the structural design and synthesis of the desired MOFs. As an important C 3 symmetry aromatic tricarboxylate ligand, 1,3,5-benzenetricarboxylic acid (H 3 btc) has been widely used to construct MOFs with opened 1D channels and nanocages, which not only exhibit excellent gas storage and separation properties but also show excellent luminescent sensing properties for detection of Fe 3 + , harmful organic solvents, and nitroaromatic explosives etc.. [22][23][24][25] Up to now, only Mg, Ca or Badoped Zn(II)-1,3,5-benzenetricarboxylate compounds have been reported, [26][27][28] and the Sr-doped Zn(II)-1,3,5-benzenetricarboxylate compound has not been synthesized and structurally characterized.…”