Abstract. We investigate some Diophantine approximation constants related to the simultaneous approximation of (ζ, ζ 2 , . . . , ζ k ) for Liouville numbers ζ. For a certain class of Liouville numbers including the famous representative n≥1 10 −n! and numbers in the Cantor set, we explicitly determine all approximation constants simultaneously for all k ≥ 1.