In this paper, we consider the new q-extension of Frobenius-Euler numbers and polynomials and we derive some interesting identities from the orthogonality type properties for the new q-extension of Frobenius-Euler polynomials. Finally we suggest one open question related to orthogonality of polynomials.1991 Mathematics Subject Classification. 11B68, 11S80. Key words and phrases. q−umbral algebra, q−umbral calculus, n−th ordinary Frobenius-Euler polynomials.. 1