Abstract:Owing to high natural abundance and relatively low redox potential of potassium (K), the K-ion battery (KIB) is a compelling substitute technology for the currently used lithium-ion battery (LIB). In...
“…Raman spectroscopy was used to analyze the carbon contents of the different cathode materials: NVP, NVCP, NVFP, and NVCFP. The Raman spectra of both cathodes exhibited D and G bands at 1375 and 1600 cm −1 , respectively, which are characteristic of carbon with dominant disorder sp2 Raman features 43 (Figure S6). The CHN analysis was used to determine the carbon contents of the two cathode materials.…”
Cationic alteration related to a sodium super ion conductor (NASICON)-structured Na 3 V 2 (PO 4 ) 3 (NVP) is an effective strategy for formulating high-energy and stable cathodes for sodium-ion batteries (SIBs). In this study, we altered the structure of NVP with dual cations, namely, Cr and Fe, to develop Na 3 V 1.5 Cr 0.4 Fe 0.1 (PO 4 ) 3 cathodes for SIBs with high-rate capability (∼71 mAh g −1 at 100 C) and an extreme cycle life output (∼75 mAh g −1 with 95% capacity retention for 10,000 cycles). These excellent electrochemical properties can be ascribed to the synergistic effects of Cr and Fe in the NVP structure, as verified experimentally and theoretically. Therefore, the proposed cosubstitution method can enhance the performance of SIBs by improving their structural stability, electronic conductivity, and phase-change behavior.
“…Raman spectroscopy was used to analyze the carbon contents of the different cathode materials: NVP, NVCP, NVFP, and NVCFP. The Raman spectra of both cathodes exhibited D and G bands at 1375 and 1600 cm −1 , respectively, which are characteristic of carbon with dominant disorder sp2 Raman features 43 (Figure S6). The CHN analysis was used to determine the carbon contents of the two cathode materials.…”
Cationic alteration related to a sodium super ion conductor (NASICON)-structured Na 3 V 2 (PO 4 ) 3 (NVP) is an effective strategy for formulating high-energy and stable cathodes for sodium-ion batteries (SIBs). In this study, we altered the structure of NVP with dual cations, namely, Cr and Fe, to develop Na 3 V 1.5 Cr 0.4 Fe 0.1 (PO 4 ) 3 cathodes for SIBs with high-rate capability (∼71 mAh g −1 at 100 C) and an extreme cycle life output (∼75 mAh g −1 with 95% capacity retention for 10,000 cycles). These excellent electrochemical properties can be ascribed to the synergistic effects of Cr and Fe in the NVP structure, as verified experimentally and theoretically. Therefore, the proposed cosubstitution method can enhance the performance of SIBs by improving their structural stability, electronic conductivity, and phase-change behavior.
“…455 Furthermore, doping is often accompanied by a widening of the interlayer spacing, which promotes the insertion/extraction of potassium ions in the carbon anode, thereby improving the potassium storage capacity. [465][466][467][468][469][470] In 2016, Share et al 377 successfully increased the potassium storage capacity of graphite from the theoretical maximum value of 279 mA h g À1 to 350 mA h g À1 by doping nitrogen into few-layer graphene (Fig. 35a and b).…”
“…1–4 Presently, they are in urgent need of cathode materials which can offer high specific capacity and long-term cycling stability to support large-scale applications. 5–7 Potential cathode categories, such as transition metal oxides, 8,9 polyanionic materials, 10–12 Prussian blue analogs, 13,14 and organic compounds, 15–17 have been extensively investigated. 3,6,18,19 Layered transition metal oxides (K x TMO 2 , TM = transition metal) stand out owing to their unique intercalation mechanism, high theoretical capacity and flexible elemental composition advantages.…”
Manganese based layer-structured transition-metal oxides are highly regarded as excellent cathode materials for potassium-ion batteries (KIBs) for their excellent industrial processing feasibility and high voltage platform. However, the energy density...
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