An amidoxime-group-containing adsorbent for the recovery of uranium from seawater was synthesized by radiation-induced graft polymerization of acrylonitrile onto polypTopylene fiber of round and cross-shaped sections. The tensile strength and elongation of the synthesized adsorbent, both of which were onehalf those of the raw material, were not affected by the shape of the fiber. The deterioration of the adsorption ability induced by immersing the adsorbent in HCI was negligible because of the short immersion time required for the desorption with HCI. The concentration factors for uranium and transition metals in 28 days were in the order of lo5, while those for alkali metals and alkaline earth metals were in the order 10-'-10'. The recovery of uranium with the cross-shaped adsorbent was superior to that of the round-shaped one. X M A line profiles show that the distribution of uranium is much restricted to the surface layer when compared with that of alkaline earth metals. Diminishing the diameter or increasing the surface area was effective for increasing the adsorption of uranium.
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