“…Conversion to the acylamino side chain is then possible. Other variations using ketenimines have been reported (190,191). One other method using imines involves addition to the quinonoid intermediate (219), derived by oxidation of the corresponding phenolic Schiffs base (192).…”
“…Conversion to the acylamino side chain is then possible. Other variations using ketenimines have been reported (190,191). One other method using imines involves addition to the quinonoid intermediate (219), derived by oxidation of the corresponding phenolic Schiffs base (192).…”
Die Behandlung der Vinylidenamino‐cephalosphorine (I) mit Brom in Tetrahydrofuran bei ‐20°C bis 30°C und anschließend mit methanolischem Lithiummethylat bei ‐78°C ergibt die Methoxycephalosporine (II).
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