A new synthesis of triazane derivatives

Abstract

Finally, the rearrangement of the thiosemicarbazone to give the isothiocyanate is the only case to date in which a thioamide or thiourea has undergone the Hofmann reaction.(PH 5-7).

Mechanistic Studies of a Linear Trisazoalkane, a New Azimine, and a Bicyclic Triaziridine. Azoalkane Homolysis into Seven Fragments

“…The details of the correlated spectra verify the structures assigned to 9 and 10 , which are fully rationalized elsewhere . An online search of Beilstein uncovered only two compounds ( 11a , b ), whose structure resembles 10 …”