A new square pyramidal copper(II) complex [Cu(C10H24N4)Br]Br: Crystal structure, thermal analysis, Hirschfeld surfaces, electrical and semiconducting properties

Binuclear Cu complex catalysis enabling Li–CO2 battery with a high discharge voltage above 3.0 V

“…3b ). The absorbance band matches well with the d–d transition of Cu 2+ center in the bridged CO 2 -derived oxalate group 52 . And a new peak at 2332 cm −1 referring to the vibration mode of ν s (O−C=O) + δ s (O−C=O) in oxalate group is recorded in the Raman spectrum 49 (Fig.…”

Supramolecular architectures of mononuclear nickel(II) and homobinuclear copper(II) complexes with the 5,5′-dimethyl-2,2′-bipyridine ligand: Syntheses, crystal structures and Hirshfeld surface analyses

“…[16][17][18][19][20][21][22][23] Moreover, a large number of studies showed that postsynthetic functionalization or direct syntheses with ligands having suitable functionality can impart hydrogen bond capabilities to the organic-inorganic hybrid. 24,25 Besides, one of the most widely studied functional groups that have been used to impart hydrogen bonding capabilities to the hybrid is the amino, carbonyl, anhydride, cyano group, etc., [26][27][28][29][30] Even more recently, the self-assembly processes are sensitive to diverse synthetic conditions in some cases, change of reaction conditions such as the solvent, pH and temperature for a given set of organic ligands and metal ions can cause various supramolecular architectures. 31,32 In this regard, solvent molecules or counter-ions (CH3COO -, NO3, NO2, ClO4 -, etc) may also dramatically influence the overall solid-state architecture Please do not adjust margins Please do not adjust margins by participating in metal coordination and hydrogen bonding.…”