The clay mineral
composition of four brown forest soil profiles (Luvisols) developed on
different parent rocks was studied in detail to determine the major clay
mineral alteration processes. In the studied profiles a siltstone bedrock
weathered to chlorite/vermiculite and vermiculite in a less developed, shallow
soil profile, while the major product of soil formation in a clayey,
well-developed deep soil is a typical soil montmorillonite with heterogeneous
charge distribution. The most possible pathway of clay alteration is illite
smectitization via charge reduction, and considerable degradation of smectite
in the soil formed on limestone. On the contrary, weathering of andesite parent
rock involves the formation of low charged smectite altering to high charged vermiculite
during pedogenesis.