A new room temperature molten salt solvent system: organic cation tetrachloroborates

Williams, Stephen D.; Schoebrechts, Jean‐Paul; Selkirk, J. C.; Mamantov, G.

doi:10.1021/ja00241a069

Cited by 29 publications

(7 citation statements)

References 3 publications

(3 reference statements)

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“…The trichlorocyanoborates Kt [BCl 3 (CN)] were prepared in a two‐step procedure. The reaction of organic salts Kt + Cl – ( Kt + = organic cation) with BCl 3 resulted in the formation of organic salts with the [BCl 4 ] – anion (Scheme , A) , . Treatment of Kt [BCl 4 ] with trimethylsilyl cyanide (CH 3 ) 3 SiCN led to the substitution of one chlorine by a cyano group, yielding the corresponding salts of the [BCl 3 (CN)] – anion (Scheme , B) …”

Section: Chlorocyanoborates Kt[bcl4–x(cn)x](x = 1 2 3)mentioning

confidence: 99%

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Cyanoborates

Ignat’ev

Finze

2019

Eur J Inorg Chem

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Cyanoborate chemistry has emerged to an important topic during the last two decades, beginning with two independent reports on the successful synthesis of the tetracyanoborate anion [B(CN) 4 ]in 2000. A wealth of cyanoborate anions with different substituents in addition to CN group(s) bonded to boron, i.e. hydrogen, halogen, aryl, alkenyl, alkyl, perfluoroalkyl, and alkoxy, have been developed, which enable the tuning of properties of compounds and materials based on them. The readily accessible alkali metal cyanoborates are convenient starting materials for the preparation of cyanoborates with various organic, inorganic, and metal cations as well as cyanoborate coordination compounds. A focus has been on low-[a] Julius-Maximilians-Universität Würzburg,

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Section: Chlorocyanoborates Kt[bcl4–x(cn)x](x = 1 2 3)mentioning

confidence: 99%

“…Measured near room temperature; the electrochemical window was measured using a setup with a glassy carbon working electrode. [112a]…”

Section: Physical Properties Of Cyanoborate‐ilsmentioning

confidence: 99%

Cyanoborates

Ignat’ev

Finze

2019

Eur J Inorg Chem

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“…Chloroaluminate anions form RTILs with various organics, including not only EMI and BP but also triazolium [51] and aliphatic onium cations [7,[52][53][54]. Other unique RTILs similar to the chloroaluminate systems such as the chlorogallate (GaCl 4 À ) [55], chloroborate (BCl 4 À ) [56], and bromoaluminate (AlBr 4 À ) systems [57] have been reported.…”

Section: Chloroaluminate Systemsmentioning

confidence: 99%

Electrochemical Windows of Room‐Temperature Ionic Liquids

Matsumoto¹

2005

Electrochemical Aspects of Ionic Liquids

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“…Such salts involve simple mixing of the Lewis acid and the halide salt which results in the formation of more than one anionic species depending upon the ratio of quaternary halide salt Q + X [29], CuCl [30], and InCl 3 [31] to mention a few.…”

Section: Introductionmentioning

confidence: 99%

Ionic Liquids: Synthesis and Applications in Catalysis

Rajni

2014

Advances in Chemistry

211

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Ionic liquids have emerged as an environmentally friendly alternative to the volatile organic solvents. Being designer solvents, they can be modulated to suit the reaction conditions, therefore earning the name "task specific ionic liquids. " Though primarily used as solvents, they are now finding applications in various fields like catalysis, electrochemistry, spectroscopy, and material science to mention a few. The present review is aimed at exploring the applications of ionic liquids in catalysis as acid, base, and organocatalysts and as soluble supports for catalysts.

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A new room temperature molten salt solvent system: organic cation tetrachloroborates

Cited by 29 publications

References 3 publications

Cyanoborates

Cyanoborates

Electrochemical Windows of Room‐Temperature Ionic Liquids

Ionic Liquids: Synthesis and Applications in Catalysis

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