A new platform for the post-functionalization of porous polymer based on calix[4]resorcinarene under thermal solvent-free conditions; as a highly efficient and recyclable PTC containing nanocavity
Abstract:In this work, for the first time, functionalized 3D-network polymer was synthesized through thermal solvent-free method. The synthetic steps include (1) the preparation of ionic liquid (1-methyl-3-(trimethoxysilylpropyl) imidazolium choloride) [pmim]Cl, (2) synthesis of the 3D-network polymer based on calix[4]resorcinarene, and finally (3) immobilization of ionic liquid on the synthesize polymer through one-pot solvent-free conditions. The formation of this cationic porous polymer was confirmed by elemental an… Show more
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