Abstract:A new oxidatively stable (S)-N-benzylproline-derived ligand ((S)-N-(2-benzoyl-5-tert-butylphenyl)-1-benzylpyrrolidine-2-carboxamide) and its Ni(II)–Schiff base complexes formed of glycine, serine, and dehydroalanine are reported. A bulky tert-butyl substituent in the phenylene fragment precludes unwanted oxidative dimerization of the Schiff base complex, making it suitable for targeted electrochemically induced oxidative modification of the amino acid side chain. Experimental and DFT studies showed that the ad… Show more
“…They are used exclusively as catalysts in reactions, including both organic substances [6,7] and metal complexes [8][9][10]. A summary of the paper title exemplifies the target response of the latest report.…”
Section: (3) Reactions Involving Schiff Bases or Their Metal Complexesmentioning
confidence: 99%
“…New oxidatively stable ligands for the chiral functionalization of amino acids in Ni(II)-Schiff base complexes [9].…”
Section: (3) Reactions Involving Schiff Bases or Their Metal Complexesmentioning
“…They are used exclusively as catalysts in reactions, including both organic substances [6,7] and metal complexes [8][9][10]. A summary of the paper title exemplifies the target response of the latest report.…”
Section: (3) Reactions Involving Schiff Bases or Their Metal Complexesmentioning
confidence: 99%
“…New oxidatively stable ligands for the chiral functionalization of amino acids in Ni(II)-Schiff base complexes [9].…”
Section: (3) Reactions Involving Schiff Bases or Their Metal Complexesmentioning
The first asymmetric synthetic route to artificial α-amino acids with a 3,4-dihydroisoquinolone skeleton was elaborated via a straightforward Rh(iii)-catalyzed C–H activation/annulation reaction.
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