Abstract:The asymmetric unit of the title organic–inorganic hybrid complex [systematic name: ethane-1,2-diaminium hexachloridostannate(IV)–4-methoxybenzaldehyde (1/2)], (C2H10N2)[SnCl6]·2C8H8O2, contains one half of an ethylenediammonium cation, one half of an [SnCl6]2− anion and one p-anisaldehyde molecule. Both the organic cation and the quasi-regular octahedral inorganic anion are located about inversion centres. The organic cations and [SnCl6]2− anions lie in layers parallel to the ac plane with p-anisaldehyde mole… Show more
C10H16N2SnCl6, monoclinic, I2 (no. 5), a = 14.0477(4) Å, b = 8.9140(2) Å, c = 27.6199(6) Å, β = 93.060(2)°, Z = 8, V = 3453.67(15) Å3, R
gt
(F) = 0.0395, wR
ref
= 0.0858, T = 290 K.
C10H16N2SnCl6, monoclinic, I2 (no. 5), a = 14.0477(4) Å, b = 8.9140(2) Å, c = 27.6199(6) Å, β = 93.060(2)°, Z = 8, V = 3453.67(15) Å3, R
gt
(F) = 0.0395, wR
ref
= 0.0858, T = 290 K.
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