Our understanding of turbulent boundary layer scaling and structure has advanced greatly in the past 20 to 30 years. On the computational side, direct numerical simulations and large-eddy simulations have made extraordinary contributions as numerical methods and computational resources have advanced, while on the experimental side major advances in instrumentation have made available new imaging and quantitative techniques that provide unprecedented accuracy and detail. Here, I illustrate how the development of such experimental methods have aided our progress by reference to some particular topics related to the structure of turbulent boundary layers: the power law scaling of the mean velocity and its relationship to the mesolayer; the scaling of the outer layer with regard to the log law in turbulence; the development of the outer peak; and the scaling of the turbulent stresses in the near-wall region, with an emphasis on the streamwise component.