A new metal–organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior

Zhang, Zhongyue; Zhao, Huaiqing; Matsushita, Michio M.; Awaga, Kunio; Dunbar, Kim R.

doi:10.1039/c3tc31577k

Cited by 22 publications

(11 citation statements)

References 40 publications

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“…Infrared and Raman spectroscopy have previously been used to gain insight into the redox state of the TCNQ moiety. 35 Table 2 presents key data for complexes 1-6 together with some corresponding literature data for comparison. The spectra and number of bands reported here are consistent with previous literature reports.…”

Section: Resultsmentioning

confidence: 99%

Crown ether alkali metal TCNQ complexes revisited – the impact of smaller cation complexes on their solid-state architecture and properties

et al. 2019

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Section: Resultsmentioning

confidence: 99%

Crown ether alkali metal TCNQ complexes revisited – the impact of smaller cation complexes on their solid-state architecture and properties

et al. 2019

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“…Frameworks based on mixed-valence Ru II/III paddlewheels bridged by polycyanide ligands such as TCNQ and its derivatives also exhibit a wide range of redox-dependent properties including antiferromagnetic coupling, long range ferromagnetic ordering and magnetism. [161][162][163] These handful of examples, whilst limited in number, demonstrate the enormous future potential that exists for exploiting the different redox states of MOFs to tune magnetic properties of relevance to the development of new magnetoelectric devices for data storage applications, amongst others. 59,63…”

Section: Multifunctionality: the Interplay Between Redox Activity And...mentioning

confidence: 99%

Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives

2016

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Of the many thousands of new metal-organic frameworks (MOFs) that are now discovered each year, many possess potential redox activity arising from the constituent metal ions and/or organic ligands, or the guest molecules located within their porous structures. Those redox states that can be accessed via postsynthetic redox modulation often possess distinct physical properties; if harnessed, these provide a basis for applications including microporous conductors, electrocatalysts, energy storage devices and electrochemical sensors, amongst others. This feature article highlights the latest developments in experimental, theoretical and computational concepts relevant to redox-active MOFs, including new solid state electrochemical and spectroelectrochemical techniques that have great utility in this field. A particular emphasis is on current and emerging trends at the fundamental level which underscore the importance of this promising class of electroactive materials for a wide range of technologically- and industrially-relevant applications.

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“…The first crystallographically independent metalloligand coordinates to one Ag(2) and three Ag(1) ions, and the second one to one Ag(2) and three Ag(3) ions. As a result, the Ag(2) ions links two interpenetrating CPs of the stoichiometry [Ag (5)] and the utp topology (widespread among 3-coordinated CP nets) 19 to form a three-dimensional net. A topological analysis of the resulting architecture by means of the ToposPro package 20 revealed that the net has a point symbol (8•10 2 )(8 2 •10 4 )(8 2 •10)(8 3 •10 3 ).…”

Section: Coordination Polymers With Silver(i)mentioning

confidence: 99%

Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands

et al. 2016

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Dinuclear clathrochelate complexes with two, three, four, or five cyano groups in the ligand periphery were prepared following two distinct synthetic strategies: (a) zinc(ii)- or cobalt(ii)-templated polycondensation reactions of CN-functionalized arylboronic acids and phenoldioximes, or (b) postsynthetic cross-coupling reactions of polybrominated zinc(ii) clathrochelates with 4-cyanophenylboronic acid. The new clathrochelate complexes were used as metalloligands for the construction of heterometallic Zn/Ag and Co/Ag coordination polymers (CPs), which were characterized by single crystal X-ray diffraction and FT-IR. A one-dimensional CP was observed for ditopic clathrochelates, whereas two- and three-dimensional CPs were generated from tetra- and pentatopic metalloligands. The three-dimensional network is unique as it displays an unprecedented network topology with the point symbol (8·10)(8·10)(8·10)(8·10). Furthermore, it is a self-catenated net with an extremely high topological density.

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A new metal–organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior

Cited by 22 publications

References 40 publications

Crown ether alkali metal TCNQ complexes revisited – the impact of smaller cation complexes on their solid-state architecture and properties

Crown ether alkali metal TCNQ complexes revisited – the impact of smaller cation complexes on their solid-state architecture and properties

Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives

Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands

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