A new kind of hierarchical porous zirconium phosphonate: preparation and application on oxidation catalysis
Shan Fu,
Yi Tian,
Xin Long
et al.
Abstract:A kind of new zirconium phosphonate material (named as ZrDP) with multilevel porous structure and high surface area (about 408.6 m2/g) was synthesized by the reaction between 1,4,7,10-Tetraazacyclododecane-1,4,7,10-tetrayl- tetrakis(methylphosphonic acid) (DOTMP) and zirconium dichloride oxide octahydrate. Microporous structure (diameter about 0.64 nm) from 1,4,7,10- Tetraazacyclododecane in DOTMP and structural pores with diameter about 1.68 nm were found in the material. A series of metal coordination struct… Show more
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