2022
DOI: 10.1002/prep.202100371
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A New High Order Virial Equation of State and Its Application in the Chapman‐Jouguet Parameters Calculation of Explosives

Abstract: In this paper, in order to solve the deficiency of VLW (Virial‐Wu) equation of state (EOS) and VHL (Virial‐Han‐Long) EOS in describing thermodynamic relationship in high temperature region of gaseous detonation products. Based on the Mayer expansion theory of gas virial coefficients in statistical mechanics, the fourth‐order and fifth‐order dimensionless virial coefficients for Lennard‐Jones (L−J) 6–12 pair potential in a higher temperature range are calculated by using the orthogonal integral method which pro… Show more

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Cited by 3 publications
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“…Thermochemical equations of state such as BKW [ 8 ], WCA [ 9 ], and VLW [ 10 ] consider the chemical reaction process and composition change. Although such equations of state are widely used in basic scientific calculations, their computational intensity impedes their application in finite or discrete element programs aiming to characterize explosive work capacity [ 11 , 12 , 13 , 14 , 15 ]. Thus, by calibrating coefficients of semi-empirical equations of state via the chemical reaction perspective both computational efficiency and reliability can be taken into account.…”
Section: Introductionmentioning
confidence: 99%
“…Thermochemical equations of state such as BKW [ 8 ], WCA [ 9 ], and VLW [ 10 ] consider the chemical reaction process and composition change. Although such equations of state are widely used in basic scientific calculations, their computational intensity impedes their application in finite or discrete element programs aiming to characterize explosive work capacity [ 11 , 12 , 13 , 14 , 15 ]. Thus, by calibrating coefficients of semi-empirical equations of state via the chemical reaction perspective both computational efficiency and reliability can be taken into account.…”
Section: Introductionmentioning
confidence: 99%