A new family of oxime palladacycles mixed with unsymmetrical phosphorus ylides; synthesis, structural, cytotoxicity and catalytic activity studies

Samiee, Sepideh; Shiralinia, Ahmadreza; Hoveizi, Elham; Gable, Robert W.

doi:10.1016/j.jorganchem.2019.120927

Cited by 13 publications

(8 citation statements)

References 47 publications

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“…Nowadays, the coordination chemistry of vic-dioximes is interesting due to stable, easy to prepare, highly colored complexes with a large structural diversity, very efficient and versatile biological properties, and thus numerous transition metal complexes of these ligands have been investigated in detail. [1,2] The chemistry of vic-dioximes and their numerous transition metal complexes are being used as coordination compounds, and also there are lots of usage areas, such as analytical, [3] biological systems, [4,5] and medicinal chemistry. [2] Many researchers have studied vicdioximes which have an important role in the complexes especially 1, 2-dioximes in coordination chemistry.…”

Section: Introductionmentioning

confidence: 99%

“…[1,2] The chemistry of vic-dioximes and their numerous transition metal complexes are being used as coordination compounds, and also there are lots of usage areas, such as analytical, [3] biological systems, [4,5] and medicinal chemistry. [2] Many researchers have studied vicdioximes which have an important role in the complexes especially 1, 2-dioximes in coordination chemistry. [6,7] Their metal complexes have been the source, through the decades, of a never-ending series of reports.…”

Section: Introductionmentioning

confidence: 99%

“…[13][14][15] These findings led us to synthesize a novel vic-dioxime ligand (1) and associated (2), ( 3), ( 4), (5), and ( 6) metal complexes, we also examined the antimicrobial and antioxidant behavior of these new types of compounds. In this article, we report the synthesis, structural characterization of the novel vic-dioxime ligand (1) and its metal complexes (2)(3)(4)(5)(6). In a continuation of our work vic-dioxime ligand (1) and its metal complexes (2)(3)(4)(5)(6) were tested for their in-vitro antibacterial and antioxidant activities.…”

Section: Introductionmentioning

confidence: 99%

“…In this article, we report the synthesis, structural characterization of the novel vic-dioxime ligand (1) and its metal complexes (2)(3)(4)(5)(6). In a continuation of our work vic-dioxime ligand (1) and its metal complexes (2)(3)(4)(5)(6) were tested for their in-vitro antibacterial and antioxidant activities.…”

Section: Introductionmentioning

confidence: 99%

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Preparation of Cu(II), Ni(II), Ti(IV), VO(IV), and Zn(II) Metal Complexes Derived from Novel vic‐Dioxime and Investigation of Their Antioxidant and Antibacterial Activities

Alhafez

Savcı

Alan

et al. 2022

Chemistry & Biodiversity

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In this work, novel vic-dioxime ligand (LH 2 ) containing bound to the N 4 -oxime core moiety and its complexes with Cu(II), Ni(II), Ti(IV), VO(IV), and Zn(II) salts have been studied. The structure of the ligand and its complexes were successfully synthesized and characterized using NMR ( 1 H and 13 C), LC/MS/MS spectrometer, FT-IR and UV/ VIS spectroscopy, melting point, and magnetic susceptibility measurements. Vic-dioxime ligand (LH 2 ) (1) and its metal complexes ([Cu(LH) 5), and [Zn(LH) 2 ] (6), respectively) were tested for them in-vitro antibacterial and antioxidant activities. According to the metal chelating results of the study, it was determined that compounds (1), ( 2), ( 3), and ( 6) showed very good activity, and especially compound (2), had a stronger metal chelating capacity due to ligand dissociation from the synthesized metal complexes, which then would chelate Fe(II) in the experimental setting. When microorganisms were evaluated in terms of the % viability effect, it was observed that all compounds had activity against C. Albicans and S. Cerevisiae at rates similar to antibiotics.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Preparation of Cu(II), Ni(II), Ti(IV), VO(IV), and Zn(II) Metal Complexes Derived from Novel vic‐Dioxime and Investigation of Their Antioxidant and Antibacterial Activities

Alhafez

Savcı

Alan

et al. 2022

Chemistry & Biodiversity

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“…Other important property of these compounds is their catalytic activity [13][14][15]. This is very important in chemical and pharmaceutical industry, being used as catalysts in a lot of reactions.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of mono- and dinuclear cyclometallated compounds with palladium and platinum

Rúa‐Sueiro

Munín‐Cruz

Reigosa

et al. 2020

Proceedings of the 24th International Electronic Conference on Synthetic Organic Chemistry

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Cyclometallated compounds, particularly with palladium and platinum, have been extensively studied over the past years in part due to their applications as catalysts in cross-coupling reactions. They are also useful in medicinal chemistry, and quite a large number have luminescent properties. Herein, the synthesis and characterization of novel palladium cyclometallated compounds and a study of their reactivity with a diphosphine ligand is discussed. Mono-and dinuclear compounds were prepared depending on phosphine ligand coordination. Characterization has been carried by IR spectroscopy, 1 H and 31 P NMR spectroscopy

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New symmetric palladacycle complexes including phosphorus ylide: synthesis, characterization, theoretical and cytotoxicity studies

Hashemi,

Yousefi,

Sabounchei

et al. 2024

Monatsh Chem

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A new family of oxime palladacycles mixed with unsymmetrical phosphorus ylides; synthesis, structural, cytotoxicity and catalytic activity studies

Cited by 13 publications

References 47 publications

Preparation of Cu(II), Ni(II), Ti(IV), VO(IV), and Zn(II) Metal Complexes Derived from Novel vic‐Dioxime and Investigation of Their Antioxidant and Antibacterial Activities

Preparation of Cu(II), Ni(II), Ti(IV), VO(IV), and Zn(II) Metal Complexes Derived from Novel vic‐Dioxime and Investigation of Their Antioxidant and Antibacterial Activities

Synthesis of mono- and dinuclear cyclometallated compounds with palladium and platinum

New symmetric palladacycle complexes including phosphorus ylide: synthesis, characterization, theoretical and cytotoxicity studies

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