A new, dinuclear high spin manganese(III) complex with bridging phenoxy and methoxy groups. Structure and magnetic properties

Synthesis and Characterization of Oligonuclear Ru, Co and Cu Oxidation Catalysts

“…[4] A dinuclear Mn complex of the anion of ligand 3 (bbpmp) has been studied earlier, [5] but exploratory attempts to use this for catalytic water oxidation have failed. We therefore decided to prepare the related Ru complex 4 and test this.…”

Magnetic and Spectroscopic Study on a New Asymmetric Mixed‐valence Mn2(II,III) Coordination Compound

“…Using g Mn II = 2.0 and g Mn III = 1.9 a reasonable fit was obtained with an exchange parameter of J = –8.5 cm –1 . The result reveals that the antiferromagnetic coupling in 1 is slightly larger than in the phenolate bridged Mn II,III compound,25 which can be explained by the enlarged Mn(1)–O(1)–Mn(2) angle.…”

“…A reaction with 1H‐imidzole‐2‐methanamine gives the symmetric ligand Hbimp21 with four imidazole groups as pendants. By adding optional bis(2‐pyridylmethyl)amine (BMPA) or N ‐2‐pyridylmethyl‐ N ‐2‐hydroxybenzylamine (HPPA) the two symmetric ligands Hbpmp,22,23 H 3 bhpp,24,25 and the asymmetric ligand H 2 bpbpm19 can be synthesized. Dinuclear manganese complexes could be stabilized in three different redox states: Mn 2 (II,II), Mn 2 (II,III), and Mn 2 (III,III) 19,26.…”

New series of monoamidoxime derivatives displaying versatile antiparasitic activity

“…[24][25] We hypothesized that methoxy-group interferes with manganese acetate, therefore more equiv. of manganese (III) M A N U S C R I P T…”

“…The reaction of cyano derivatives synthesized from both cyclization mediated by manganese(III) acetate and Suzuki-Miyaura cross-coupling reactions (12)(13)(14)(15)(16)(17)(18)(19)(20)(21)(22)(23)(24)(25)(26)(27)(28)(29)(30)(31), with hydroxylamine hydrochloride and potassium tert-butoxide in DMSO [30] led to conversion of the cyano group into amidoximes 32-51 in moderate to excellent yields (28-100%) as reported in Table 4. almost halves the reaction yield.…”