2019
DOI: 10.1016/j.cej.2019.03.253
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A new design for Si wears double jackets used as a high-performance lithium-ion battery anode

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Cited by 56 publications
(27 citation statements)
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“…While the previously discussed nanostructures have made improvements for suppressing the huge volume expansion of Si-based materials, swelling-induced active material delamination from the current collector and electrode instability remain critical challenges for Si anodes. [262,263] In order to meet the commercial request, the tap density of Si-based electrode should reach ≈1.65 g cm −3 , while electrode swelling is limited to 10%. The concept of thickness swelling is an important factor for electrode design and is usually ignored for material design.…”
Section: Synergistic Techniques For Whole Electrode Stabilitymentioning
confidence: 99%
“…While the previously discussed nanostructures have made improvements for suppressing the huge volume expansion of Si-based materials, swelling-induced active material delamination from the current collector and electrode instability remain critical challenges for Si anodes. [262,263] In order to meet the commercial request, the tap density of Si-based electrode should reach ≈1.65 g cm −3 , while electrode swelling is limited to 10%. The concept of thickness swelling is an important factor for electrode design and is usually ignored for material design.…”
Section: Synergistic Techniques For Whole Electrode Stabilitymentioning
confidence: 99%
“…Besides, the R SEI represents the resistance of lithium ions entering the SEI layers [27,29,61] . There is a sloping line in low‐frequency region called Warburg resistance, which represents the lithium‐ion finally diffuse into the interspace of the electrode materials [64,65] . The R ct value of pure Si/FeSi 2 NPs electrodes is 129 Ω before cycle.…”
Section: Resultsmentioning
confidence: 99%
“…[3,4] Thereby, developing and searching for advanced anode materials with high specific capacity as candidate is extremely urgent. [1,5,6] So far, many kinds of anode materials have been used in LIBs such as nanosized carbons, [7] alloys, [8,9] metal oxides, [10][11][12][13] metal sulfides [14][15][16][17][18] and metal selenides. [19][20][21][22] Among them, SnO 2 , which is well documented in several works, is regarded as a promising candidate for commercial graphite anode because of much higher capacity (1494 mAh g À 1 ), low working potential, chemical stability as well as nontoxicity.…”
Section: Introductionmentioning
confidence: 99%
“…So far, many kinds of anode materials have been used in LIBs such as nanosized carbons, alloys, metal oxides, metal sulfides and metal selenides . Among them, SnO 2 , which is well documented in several works, is regarded as a promising candidate for commercial graphite anode because of much higher capacity (1494 mAh g −1 ), low working potential, chemical stability as well as nontoxicity .…”
Section: Introductionmentioning
confidence: 99%