1992
DOI: 10.1016/0013-4686(92)80111-x
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A new class of polymer electrolytes based on chain-extended polyepoxides and LiClO4

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Cited by 35 publications
(28 citation statements)
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“…3 , was obtained from Gelest, Inc. (x = 6-9, 90% purity) [referred to as PEO(375)-silane, since 375 was the average molecular weight calculated for the PEO segment, assuming one of the three CH 2 groups between the PEO and Si belong to the PEO moiety].…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…3 , was obtained from Gelest, Inc. (x = 6-9, 90% purity) [referred to as PEO(375)-silane, since 375 was the average molecular weight calculated for the PEO segment, assuming one of the three CH 2 groups between the PEO and Si belong to the PEO moiety].…”
Section: Methodsmentioning
confidence: 99%
“…Use of low molar mass polyethylene glycol dimethyl ethers (PEGDMEs) as plasticizers (30-40%) in the PEO matrix increased ambient temperature conductivities, but at the cost of significant reduction in the mechanical and interfacial properties [1]. Other approaches to increasing the room temperature (RT) conductivity of polyether electrolytes are by attachment of short-chain PEO oligomers as side chains to flexible [2][3][4][5][6][7][8][9][10] or rigid polymer backbones [11,12], network polyethers [13,14] and inorganic scaffolds [15,16].…”
Section: Introductionmentioning
confidence: 99%
“…Recently, comb-like polymers with oligomeric PEO in their side chains have attracted interest for use in polymer electrolytes [6][7][8][9][10][11]. Since the pendant PEO side chains alter the matrix flexibility, fast side-chain motion increases the mobility of the dissolved ions and thus improves their conductivity.…”
Section: Introductionmentioning
confidence: 99%
“…[6][7][8][9] To suppress crystallinity and increase segmental mobility of the ethylene oxide chain, PEO-based compounds with polysiloxane 6 or polyurethane 10 and branched 11 or hyperbranched ether chain 12,13 and with cross-linked networks 14,15 have been studied. These polymers need to eliminate byproducts produced in polymerization or catalysts used for polymerization which have adverse effect on their electrochemical properties.…”
mentioning
confidence: 99%