A new ultralow-temperature-sinterable BaV 2 O 6 ceramic was prepared through a conventional solid-state ceramic method. Thermogravimetric and differential-scanning-calorimetry analyses were performed to confirm the phase formation of BaV 2 O 6 . Phase purity and crystal structure of the ceramic material were studied by using X-ray diffraction analysis and Raman spectroscopic studies. BaV 2 O 6 crystallizes in an orthorhombic unit cell, and the calculated lattice parameters are a = 8.532 Å, b = 12.583 Å, and c = 7.554 Å. BaV 2 O 6 ce-