A New Aporphine Alkaloid from the Stems of Liriodendron chinense

Chen, C. Y.; Kao, C. L.; Li, W. J.; Chen, H. C.; Li, H. T.

doi:10.1007/s10600-018-2391-2

Chem Nat Compd

2018

DOI: 10.1007/s10600-018-2391-2

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A New Aporphine Alkaloid from the Stems of Liriodendron chinense

C. Y. Chen

C. L. Kao

W. J. Li

et al.

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Cited by 6 publications

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“…The roots and barks have a long history of application for the treatment of cough and arthritis . So far, only some regular germacrane- and eudesmane-type sesquiterpenes as well as a few common aporphine alkaloids from the leaves and stems of L. chinense have been reported …”

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confidence: 99%

Liriogerphines A–D, a Class of Sesquiterpene–Alkaloid Hybrids from the Rare Chinese Tulip Tree Plant

et al. 2022

J. Org. Chem.

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Liriogerphines A–D (1–4, respectively), an unprecedented class of hybrids of germacranolide-type sesquiterpenoids and aporphine-type alkaloids, were isolated from the rare medicinal plant Liriodendron chinense. Their structures were elucidated by comprehensive spectroscopic analyses combined with electronic circular dichroism calculations and X-ray crystallographic data. Biosynthetically, an aza-Michael addition reaction is proposed to be involved in the assemblies of this class of hybrids. Compound 4 exhibited cytotoxicity against leukemia cells via inducing apoptosis and inhibiting Bcl-2 expression.

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mentioning

confidence: 99%

Liriogerphines A–D, a Class of Sesquiterpene–Alkaloid Hybrids from the Rare Chinese Tulip Tree Plant

et al. 2022

J. Org. Chem.

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Chemical Constituents of Lepidium sativum Seeds

2019

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Phenolic and Acid Derivatives from Artemisia sieversiana

Chen

Nan

et al. 2021

Chem Nat Compd

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A New Aporphine Alkaloid from the Stems of Liriodendron chinense

Cited by 6 publications

References 18 publications

Liriogerphines A–D, a Class of Sesquiterpene–Alkaloid Hybrids from the Rare Chinese Tulip Tree Plant

Liriogerphines A–D, a Class of Sesquiterpene–Alkaloid Hybrids from the Rare Chinese Tulip Tree Plant

Chemical Constituents of Lepidium sativum Seeds

Phenolic and Acid Derivatives from Artemisia sieversiana

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