A Network of Processes for Biorefining Burdock Seeds and Roots
Luigi di Bitonto,
Enrico Scelsi,
Massimiliano Errico
et al.
Abstract:In this work, a novel sustainable approach was proposed for the integral valorisation of Arctium lappa (burdock) seeds and roots. Firstly, a preliminary recovery of bioactive compounds, including unsaturated fatty acids, was performed. Then, simple sugars (i.e., fructose and sucrose) and phenolic compounds were extracted by using compressed fluids (supercritical CO2 and propane). Consequently, a complete characterisation of raw biomass and extraction residues was carried out to determine the starting chemical … Show more
“…Sulfonated carbon-based catalysts are obtained by direct sulfonation of biochar with sulfuric acid (H 2 SO 4 ) by introducing sulfonic groups (-SO 3 H) as Brønsted acid sites on the surface [34][35][36]. On the other hand, magnetic carbon-based materials have emerged as a sustainable alternative to facilitate the recovery of catalysts in heterogeneously catalyzed liquid-phase reactions [37][38][39]. At the end of the use, they can easily be recovered from the reaction medium in the presence of an external magnetic field.…”
Section: Integrated Approach To Biorefinery: Development Of Heterogen...mentioning
In this work, a closed-loop strategy for the management and valorization of winery waste was proposed. The exhausted pomace and grape stalks that are typically obtained from white wine industries were used as a source of simple sugars, namely, glucose and fructose, and of lignocellulosic feedstock for the preparation of selective catalysts for the 5-hydroxymethylfurfural (5-HMF) production from fructose. A novel synthetic procedure was developed for the synthesis of iron-sulfonated magnetic biochar catalysts (Fe-SMBCs). Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), BET surface area, porous structure analysis and determination of total amount of acid sites were performed in order to characterize the physico-chemical properties of the synthesized systems. Then, these heterogeneous catalysts were successfully tested via the dehydration of simple sugars into 5-HMF by using methyl isobutyl ketone (MIBK) and gamma valerolactone (GVL) as co-solvents. The optimum 5-HMF yield of 40.9 ± 1.1%mol with a selectivity of 59.8 ± 2.6%mol was achieved by adopting the following optimized conditions: 0.1 g of catalyst, volume ratio of GVL to H2O = 2 to 1, 403 K, 6 h. In addition, the catalyst was easily recycled using an external magnetic field and used for at least five reaction cycles without significant loss of catalytic activity.
“…Sulfonated carbon-based catalysts are obtained by direct sulfonation of biochar with sulfuric acid (H 2 SO 4 ) by introducing sulfonic groups (-SO 3 H) as Brønsted acid sites on the surface [34][35][36]. On the other hand, magnetic carbon-based materials have emerged as a sustainable alternative to facilitate the recovery of catalysts in heterogeneously catalyzed liquid-phase reactions [37][38][39]. At the end of the use, they can easily be recovered from the reaction medium in the presence of an external magnetic field.…”
Section: Integrated Approach To Biorefinery: Development Of Heterogen...mentioning
In this work, a closed-loop strategy for the management and valorization of winery waste was proposed. The exhausted pomace and grape stalks that are typically obtained from white wine industries were used as a source of simple sugars, namely, glucose and fructose, and of lignocellulosic feedstock for the preparation of selective catalysts for the 5-hydroxymethylfurfural (5-HMF) production from fructose. A novel synthetic procedure was developed for the synthesis of iron-sulfonated magnetic biochar catalysts (Fe-SMBCs). Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), BET surface area, porous structure analysis and determination of total amount of acid sites were performed in order to characterize the physico-chemical properties of the synthesized systems. Then, these heterogeneous catalysts were successfully tested via the dehydration of simple sugars into 5-HMF by using methyl isobutyl ketone (MIBK) and gamma valerolactone (GVL) as co-solvents. The optimum 5-HMF yield of 40.9 ± 1.1%mol with a selectivity of 59.8 ± 2.6%mol was achieved by adopting the following optimized conditions: 0.1 g of catalyst, volume ratio of GVL to H2O = 2 to 1, 403 K, 6 h. In addition, the catalyst was easily recycled using an external magnetic field and used for at least five reaction cycles without significant loss of catalytic activity.
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