A Natural Zeolite Developed with 3-Aminopropyltriethoxysilane and Adsorption of Cu(II) from Aqueous Media

Abstract

In this work, we removed copper (II) from an aqueous solution by using zeolite modified with a silicon-organic monomer (3-aminopropyltriethoxysilane; APTES) depending on the pH, time, temperature, and initial concentration of Cu(II) ions. To confirm the modification process and assess the interaction between the modified zeolite and Cu(II), we performed instrumental analyses (XRD, SEM/EDX, TGA/DTA, BET, FT-IR, and XPS). We determined the maximum adsorption capacities of the modified zeolite for Cu(II) to be 4.50, 6.244, 6.96, and 20.66 mg/g at T = 25 °C (pH = 5, t = 8 h) when the initial concentrations of Cu(II) were 50, 100, 200, and 400 mg/L, respectively. According to the adsorption thermodynamics and kinetics, the second-order reaction controls the adsorption process. Based on the two isotherm models (Langmuir and Freundlich) with constant values (KL = 0.144, n = 2.764) and the correlation coefficients (R2 = 0.8946, R2 = 0.9216), we concluded that the Cu(II) adsorption onto the modified zeolite could be followed by the Freundlich isotherm model rather than the Langmuir isotherm model. The modified zeolite could be an effective material for the removal of Cu(II) from aqueous solutions.

One-Step Synthesis of Nitrogen-Doped Porous Biochar Based on N-Doping Co-Activation Method and Its Application in Water Pollutants Control

“…When the Freundlich isotherm was used to fit the data, the correlation coefficients R 2 were 0.9976 for BBB and 0.9959 for N-BBB; while the n F values of BBB and N-BBB were 3.76 and 2.77. The results indicated that the adsorption processes were non-uniform multilayer [ 42 , 43 , 44 ].…”

Modification of natural zeolites and their applications for heavy metal removal from polluted environments: Challenges, recent advances, and perspectives

“…In recent years, natural zeolites received considerable attention due to their natural abundance, unique properties, low cost, non-toxicity, attractive physicochemical properties and efficiency in the adsorption of common pollutants [ 2 ] such as heavy metals, other inorganic compounds (ammonium, nitrites, nitrates, etc.) [ [3] , [4] , [5] , [6] , [7] , [8] , [9] ] and organic pollutants (pesticides, dyes, total petroleum hydrocarbons, etc.) [ [10] , [11] , [12] , [13] , [14] ].…”